含黄原酸、磷酸酯和席夫碱等配合物的合成、晶体结构及性能分析-材料化学专业论文.docxVIP

Y5300zI Y 5300zI 博士论文 含黄原酸盐，磷酸酯和席夫碱等配合物的合成，晶体结构及性能研宄 摘要 合成了九种脂肪族及芳香族黄原酸钠，并将它们与各种过渡金属盐反应后与邻 菲咯啉，三苯基膦等中性配体进行加合反应。通过IR，UV，DTA，NMR及单晶x一射 线衍射等谱学手段研究了它们的配位性能。结果发现，脂肪族黄原酸钠的产率明显 高于芳香族黄原酸钠，且合成温度较低。脂肪族黄原酸过渡金属盐较易与邻菲咯啉， 三苯基膦等中性配体发生加合反应，反应能力随着烷烃上R基团的增大而减弱。而 芳香族黄原酸盐因为空间位阻大，不易与上述配体发生加合反应。用单晶x一射线衍 射测定得到了异丙基黄原酸镍与邻菲咯啉的加合物的晶体结构及异丙基黄原酸钻 的晶体结构。 通过萃取法研究了两类黄原酸盐对废固分子筛催化剂中钯的萃取性能，结果发 现，芳香族黄原酸钠对钯的萃取效果明显优于脂肪族黄原酸钠。 合成并通过单晶 x一射线衍射测定得到了配合物 [[N1(phen)，]NO。·C2}150P(0)0·3心0]的晶体结构。 合成了四种席夫碱并研究了它们与过渡金属的配位性能。测定得到了N，N一2一 羟基苯亚甲基一4一氯苯亚胺铜配合物的晶体结构。 关键词：黄原酸盐，席夫碱，磷酸酯，配合物，晶体结构 ‘中英文摘要 ‘ 中英文摘要 博士论文 —————————————————————————————————’。。-________________-_-●●-。。。-_。______-____________●______-。。。_-●__-__-●-。_。●。。_-。--_-●一 ABSTRACT Nine kinds of alkyl and aryl xanthate salts were synthesized and their adducting performance with neutural 1igands such as phenanthr01ine or dipyridine was studied．The complexes were characterized by elemental analysiS，infrared spectrUm，ultraviolet spectrum．Their stability has been characterized by thermal analysis．Their crystal structure was determined by X—ray crystalIography．The results show that alkyl xanthate was synthesized at lower temperatures(10—20℃)than aryl xanthate(60-80℃)and the yield of alkyl xanthate salts were higher than the aryl ones．The aryl xanthate salts are difficult to adduct to the neutral ligands owing to steric hindrance while the alkyl xanthate salts are easy to coordinate to those l igands．The crystal structures for the complexes bis(isopropylxanthato) bis(1，10一phenanthroline)Nickel(II)and tris(isopropylxanthato)cobalt(1lI) have been determinated． The extracting qualities of two kinds of xanthates salts to precious metal Pd from the industrial waste catalysts were studied by the extracting method．The results show that extracting efficiency of aryl xanthate salts was obviously better than that of fatty xanthate salts． The complex ethyl phosphite nitrate tris(1，10一phenanthroline)nickel(II) SOlvate trihydrate WaS synthesized and its crysta