CuFe2O4载氧体的释氧特性及其对煤化学链气化的影响.docxVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：184199 CuFe2O4载氧体的释氧特性及其对煤化学链气化的影响 张将，沈来宏*，冯璇，王璐璐 （东南大学能源热转换及其过程测控教育部重点实验室，江苏 南京 210096） （TelEmail：220160426@seu.edu.cn） 摘要：采用燃烧合成法制备了CuFe2O4载氧体材料，通过TGA和流化床研究了CuFe2O4载氧体在不同温度下的释氧特性及其对煤化学链气化的影响，并对CuFe2O4载氧体物相组成的变化规律进行了XRD分析。结果表明，低于1179.7℃时，CuFe2O4中最多有16.7%的晶格氧转化为气相氧；在750~950℃内，CuFe2O4晶体晶格畸变产生氧缺陷是导致释氧的主要原因，随着温度升高，载氧体的失氧度从0.033增加到0.40；与新鲜的CuFe2O4载氧体相比，载氧体失氧度越高越有益于H2的产生，但反应活性变差，导致碳转化率的降低。 关键词：化学链气化；载氧体；CuFe2O4；释氧特性；失氧度 Oxygen Release Properties of CuFe2O4 Oxygen Carrier and Its Effect on Chemical Looping Gasification of Coal Zhang Jiang, Shen Laihong*, Feng Xuan, Wang Lulu (Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing 210096, Jiangsu) （TelEmail：220160426@seu.edu.cn） Abstract: The CuFe2O4 oxygen carrier materials had been prepared by combustion synthesis. The oxygen release properties of CuFe2O4 oxygen carrier at different temperatures and its effect on chemical looping gasification of coal were investigated by TGA and fluidized bed. and the XRD analysis of the changes in phase composition of CuFe2O4 oxygen carrier was performed. The results show that at most 16.7% of lattice oxygen in CuFe2O4 is converted into gas phase oxygen when the temperature is lower than 1179.7 °C. Oxygen deficiency due to lattice distortion of CuFe2O4 crystal is the main reason for oxygen release between 750°C and 950°C, and with the increase of temperature, the oxygen loss ratio of oxygen carrier increases from 0.033 to 0.40. Compared with the fresh CuFe2O4 oxygen carrier, the higher oxygen loss is more beneficial to the production of H2. However, the reactivity of oxygen carriers deteriorates, resulting in a decrease in carbon conversion. Key Words: Chemical looping gasification; Oxygen carrier; CuFe2O4 ; Oxygen release properties; Oxygen loss ratio 基金项目