DOC协同NSR催化剂存储还原NOx性能研究.docVIP

PAGE 1 中国工程热物理学会 燃烧学 学术会议论文 编号：184132 DOC协同NSR催化剂存储还原NOx性能研究 孙川，王攀*基金项目：国家自然科学基金项目，江苏省自然科学基金（B *基金项目：国家自然科学基金项目，江苏省自然科学基金（B 作者简介：王攀，男，教授，主要研究方向为发动机超低排放控制，Email：wangpan@ （江苏大学汽车与交通工程学院，江苏省 镇江市 212013） (Tel: Email: 270001076@) 摘 要：利用沉淀法和浸渍法制备了Pt/xBa/Ce0.5Zr0.5O2（x=10，15，20）催化剂，采用SEM/EDS表征技术对其进行了表征，并基于模拟气试验平台，研究了不同温度和O2浓度条件下DOC协同NSR催化剂存储还原NOx的性能影响。结果表明，NSR催化剂主要成分为C、O、Zr、Ce、Ba和Pt，且Pt/15Ba/Ce0.5Zr0.5O2催化剂的分散性最好；当温度为350 °C时，DOC有利于提高NSR催化剂的NOx还原效率，但温度进一步升高时却存在抑制作用；当O2浓度为7.5%时，DOC协同NSR催化剂的NOx还原效率达到最大，为92.73%。 关键词：DOC；NSR；NOx；模拟气试验 Research of DOC assisted NSR Catalyst on NOx storage and reduction SUN Chuan，WANG Pan，ZHANG Bo，LI Kai，CUI Chenrui (School of Automotive and Traffic Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China) Abstract: In this paper, the Pt/xBa/Ce0.5Zr0.5O2 (x=10, 15, 20) catalysts were prepared by precipitation and impregnation method. The SEM/EDS technology was adopted to characterize its prpperties. Based on the simulated gas test platform, the influence of DOC combined NSR catalyst on NOx removal property was studied under different temperatures and O2 concentrations. The results show that the elemental compositions of catalysts are C, O, Zr, Ce, Ba and Pt, and the dispersibility of Pt/15Ba/Ce0.5Zr0.5O2 catalyst is the best. When the temperature is 350 °C, DOC is beneficial to improve the NOx removal property of NSR catalyst, but the inhibited effect is found when further increasing the temperatures. The NOx conversion rate of DOC combined NSR catalyst reaches to the maximum value under the effect of 7.5% O2 concentration, which is 92.73%. Keywords: DOC; NSR; NOx; Simulated gas test 0引言 柴油机排放中的NOx不仅危害人类身体健康，同时也会造成臭氧含量下降，加剧紫外线对地球表面的辐射[[] Azis M M, Auvray X, Olsson L, et al. Evaluation of H2 effect on NO oxidati