柴油机尾气颗粒物中PAHs的定量分析-环境化学.PDFVIP

29 1 Vo.l 29, No. 1 2010 1 ENV IRONMENTAL CHEM ISTRY January 2010 PAH s* 1** 1 1 2 2 陈敏东 李 芳 李红双 张爱民 李同强 ( 1 , , 210044; 2 , , 2004 8) , . , , . , , PAH s, , , . 1 , : GB176912005. 150m l, 75m l 14h KD , 1m ,l . . 6890N /597 B (Agilen t) , : AgilentHP5M S 5% PhenylM ethyl S iloam ( 0m 250m 025m ); ; 201; 1l; : 280 , 70 , - 1 - 1 2m in, 10 m in 240 2m in, 4 m in 00 5m in. : ; 10 m l m in ; S IM , : m in; ( EI); 2 0 ; 150 . : (PFTBA); NIST05. . 2 PAH s, . , . EPA 16 PAH s 1 , 1. 1 (m g g- 1 ) 1 2 4 5 6 08685 1762 0 681 04 44 02559 02702 00582 01477 00504 00618 00 57 00 97 01626 02921 018 2 01745 01425 01498 0 182 07292 0 54 04119 0211 02422 1 569 56814 06 1 26614 04114 0547 00687 02511 00406 01615 00261 06 88 08965 09 11 04759 08517 0 22 18579 15816 29278 16826 2072 1271 06262 [ a] 06771 090 9 1 295 10529 12148 40 92 01824 17917 25679 18 47 1997 01947 [ b] ND 192 5 4547 049 ND 00857 [ k] ND 001 18901 01586 ND 01172 [ a] ND ND 01421 ND ND 00868 : ND. 1, 1 5, PAH