第十一讲 离子交换技术.ppt

* * * * * 扁桃酸结构式 扁桃酸pKa值的测定 扁桃酸pKa值测定的物理意义 扁桃酸pKa值测定方法 扁桃酸在非极性溶剂中的溶解度曲线 扁桃酸在非极性溶剂中的溶解度差值曲线 扁桃酸在极性溶剂中的溶解度曲线 扁桃酸在极性溶剂中的溶解度差值曲线 发酵液中R-扁桃酸的711-OH型离子交换提取 扁桃酸理化性质 树脂功能团 杂质影响 扁桃酸pKa=5.28 最适动态吸附条件 最适动态解吸条件 阴离子交换树脂的选择 Fig.1 Permeable curve of R,S-mandelic acid at anion resin pH =0.41 and OD220=1.236 of R,S-mandelic acid solution containing 2%NH4Cl, 1.0 Bv/h velocity of flow, 30 ml anion resin and 18 mm×300 mm column size. 711阴离子交换树脂对扁桃酸发酵液的动态吸附特性 Fig 2 Dynamic adsorption curve of R-mandelic acid and phenylglyoxilic acid from ferment broth at 711-OH anion exchange resin The dynamic adsorption condition was 6.0～7.0 pH value、70～80 mmol/L R-mandelic acid concentration、8～10 mmol/L phenylglyoxilic acid concentration，20 ml 711-OH anion resin and 18 mm×300 mm column size. The same as Fig 3- Fig 6. 711阴离子交换树脂对R-扁桃酸的动态解吸工艺的选择 Fig 4 Dynamic desorption curve of R-mandelic acid in different velocity of flow with 4%HCl Cl- MA- OH- 711阴离子交换树脂对R-扁桃酸的动态解吸工艺的选择 Fig.5 Dynamic desorption curve of R-mandelic acid in different HCl concentration with 1.5 Bv/h 711阴离子交换分离工艺的验证实验 Fig 6 Dynamic desorption curve of R-mandelic acid and phenylglyoxilic acid at 711-OH anion resin while the optimum condition 大孔吸附树脂HZ801分离发酵液中R-扁桃酸研究 扁桃酸理化性质 树脂功能团 杂质影响 扁桃酸pKa=5.28 最适动态吸附条件 最适动态解吸条件 3.1 不同流速时，HZ801对扁桃酸的动态吸附特性 Fig 1a Dynamic adsorption curve of R-mandelic acid from ferment broth at HZ801 resin in different velocity of flow The dynamic adsorption condition was 2.0 pH value、80 mmol/L R-mandelic acid concentration、6 mmol/L phenylglyoxilic acid concentration，20 ml HZ801 resin and 18 mm×300 mm column size. The same as Fig. 1b～Fig. 4. 3.1 不同流速时，HZ801对苯乙酮酸的动态吸附特性 Fig. 1b Dynamic adsorption curve of phenylglyoxilic acid from ferment broth at HZ801 resin in different velocity of flow 3.2 不同乙醇浓度对HZ801树脂上R-扁桃酸的动态解吸曲线 Fig.2 Dynamic desorption curve of R-mandelic acid at HZ801 resin in different ethanol concentration with 1.5 Bv/h 3.3不同流速时，50%乙醇对HZ801树脂上R-扁桃酸和苯乙酮酸的解吸曲线 Fig 3 Dyna