（包装印刷造纸）食品包装材料中油墨成分的迁移及溶出.pdfVIP

（包装印刷造纸）食品包装材 料中油墨成分的迁移及溶出 食品包装材料中油墨成分的迁移及溶出 摘　　要 采用食品模拟物进行迁移实验，结合固相微萃取-气相色谱质谱联用技术 （SPME/GC-MS ），建立了食品包装材料印刷油墨中两种光引发剂溶出量的测定方法。研究 了迁移温度和时间对光引发剂迁移的影响，以纯水和10%乙醇-水为食品模拟物，在 4℃和 45℃下迁移 120min 。模拟液用固相微萃取（SPME ）技术进行萃取，对萃取头、萃取温度和 时间进行了优化。利用GC-MS 对目标物进行定量分析。结果表明，二苯甲酮和 4-甲基二 2 苯甲酮在 0.03µg/L～1.0µg/L 的范围内线性关系均良好（r ≥0.99），检测限分别为 0.0012µg/L 、0.0040µg/L 。两种目标物在三个添加水平下，平均回收率为75.1%～95.6% ， 相对标准偏差均小于 11.5% 。本方法简单、快速、准确，能够满足食品包装的日常检验需 要。 关键词：食品包装材料；食品模拟物；气相色谱质谱法；光引发剂；迁移实验 Migration and dissolution of components in printing ink of food packing materials ABSTRACT Food stimulant and solid phase microextractiongas chromatography-mass spectrometry (SPME/GC-MS) were used in the abstraction experiment. A method for the determination of two kind of photoinitiators migrated from the printing ink on the surface of food packaging material has been developed. Photoinitiators in the food packaging samples were abstracted with food stimulant at the condition of 4℃、45℃、120min. The influence of temperature and time were for photoinitiators’ abstraction was studyed. Abstract was extracted by a solid phase microextraction （ SPME ） technology. Extraction-fiber, temperature and time were optimized. The target was analysised by GC-MS. The results showed that, the limit of detection for benzophenone and 4-methyl benzophenone was 0.0012µg/L and 0.0040µg/L with a good linear correlation (r2≥0.99) in the range of 0.03µg/L～ 1.0µg/L.The average recoveries of the two compounds at three spiked level of were 75.1%～ 95.6%, with the relative standard deviation were less than 11.5%. The method was simple, rapid, accurate and can satisfy the daily ins