《无机化学》课件-117_Chapter-12CoordinationCompounds-lecture1.pptVIP

Coordination Compounds ? Common ligands: water H - O - H ammonia NH3 chloride ion Cl - cyanide ion CN - Monodentate Examples: H2O, CN-, NH3, NO2-, SCN-, OH-, X- (halides), CO, O2- Example Complexes [Co(NH3)6]3+ [Fe(SCN)6]3- 单齿配体（monodentate ligand )： — the ligands possess a single donor atom and are able to occupy only one site in a coordination sphere Examples oxalate ion = C2O42- ethylenediamine (en) = NH2CH2CH2NH2 ortho-phenanthroline (o-phen,邻二氮杂菲) Example Complexes [Co(en)3]3+ [Cr(C2O4)3]3- [Fe(NH3)4(o-phen)]3+ 二齿配体（bidentate ligand )： — the ligands possess two donor atoms N - CH2- CH2 - N H H H H Ethylenediamine (en) N - CH2- CH2 - N H H H H Ethylenediamine (en) oxalate ion (草酸根) Ortho- phenanthroline (邻二氮杂菲) carbonate ion (碳酸根) bipyridine (联二吡啶) Structures of other bidentate ligands. The coordinating atoms are shown in blue. ethylenediaminetetraacetate (EDTA) = (O2CCH2)2N(CH2)2N(CH2CO2)24- Example Complexes [Fe(EDTA)]-1 [Co(EDTA)]-1 六齿配体（hexadentate ligand )： — the ligands possess six donor atoms Coordination Compounds ? Uses for EDTA Used in food products to complex metals that promote decomposition reactions (stabilizer/stabilizing agent) Used to remove toxic heavy metals from the body(antidote) Used to complex metal ions that inhibit or promote polymerization reactions Used to fight coagulation of blood (anticoagulant) Used in shampoos (detergent) Used in cosmetic (additive) Used in water treatment (purificant) EDTA Porphine(卟啉), an important chelating agent found in nature Metalloporphyrin（铁卟啉） Coordination Compounds Porphyrins are naturally occurring complexes derived from porphin. Heme (Fe2+)(亚铁血红素) Chlorophyll (Mg2+)(叶绿素) Structure of hemoglobin. The protein subunits are in red and blue, and the iron-containing heme groups in green. Myoglobin(肌红蛋白), a protein that stores O2 in cells Model of helical domains in myoglobin Inorganic Chemistry Chapter 12 Coordina