《无机化学》课件-151_Chapter16-group16elements-lecture2.pptVIP

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2023-01-17 发布于江苏
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《无机化学》课件-151_Chapter16-group16elements-lecture2.ppt

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16-2 OxygenOxygen has two allotropes, dioxygen and ozone. Dioxygen has a triplet ground state and oxidizes hydrocarbons by a radical chain mechanism. Reaction with an excited state molecule can produce a fairly long-lived singlet state that can react as an electrophile. Ozone is an unstable and highly aggressive oxidizing agent. 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen 16-2 Oxygen Hydrogen peroxideHydrogen peroxide is susceptible to decomposition by disproportionation at elevated temperatures or in the presence of catalysts.Hydrogen peroxide is a very pale blue, viscous liquid. It has a higher boiling point than water (150C) and a greater density (1.445 g cm3 at 25C). It is miscible in water and is usually handled in aqueous solution.16-2 Oxygen 16-2 Oxygen Hydrogen peroxide is a slightly stronger acid than water.Deprotonation occurs in other basic solvents such as liquidammonia, and NH4OOH has been isolated and found to consist of NH4 and HO2 ions. When solid NH4OOH melts (at 25C), the melt contains hydrogen-bonded NH3 and H2O2 molecules.16-2 Oxygen