酸性离子液催化苯与烯烃烷基化研究.pdfVIP

酸性离子液体催化苯与烯烃烷基化研究 酸性离子液体催化苯与烯烃烷基化研究 摘 要 绿色化学是 20 世纪 90 年代出现的新型交叉学科。离子液体作为一种绿色溶 剂和催化剂，是绿色化学化工领域的研究热点。目前离子液体研究的一个方向是设 计、合成出具有酸性性质的功能化离子液体以取代化学工业中常用的硫酸、盐酸等 液体酸，这种酸性离子液体在有机化学反应中可以同时起到溶剂和催化剂的作用。 论文对酸性离子液体的制备、红外表征及其某些物性作了相关研究。并对酸 性离子液体催化苯和 1-己烯的烷基化反应作了相对详细的研究，得出催化该烷基化 反应的最适离子液体、最适温度、最适时间、最适苯烯比以及最适离子液体用量。 结果表明，[Hmim] H PO 的催化性能最好。催化 1-己烯与苯的烷基化反应时 2 4 加入 10％(相对苯)的[Hmim] H PO 离子液体后烯烃转化率最高，反应的最适温度 2 4 为 60℃、最适时间为 60min、最适苯烯比为 10：1。 关键词：酸性离子液体，降烯烃，烷基化，清洁燃料 I 酸性离子液体催化苯与烯烃烷基化研究 Study on Alkylation of Benzene and Olefin Catalyzed by Acidic Ionic liquid Abstract Green chemistry is a new type of cross-disciplinary scientific subject which appeared in the 1990s. As a green solvent and catalyst, ionic liquid is the hot topic in the green chemical research frontier. It is important to design and prepare acidic ionic liquids to replace the commonly used sulfuric acid，hydrochloric acid and other liquid acid in the chemical industry. Such acidic ionic liquids can also play the role of solvent and catalyst in organic chemistry reactions. Acidic ionic liquid was prepared. Its physic chemical properties were tested and its infrared spectrum was scanned. Benzene and 1-Hexene alkylation catalyzed by the acidic ionic liquid was carried out. Catalytic ability of different acidic ionic liquid were compared. Optimal alkylation reactiom conditions such as，temperature ，reaction time ， benzene to 1-Hexene weight ratio and dosage of ionic liquid, were ditermined. Results showed tha