UHMWPE 粉末作为MC 铸型尼龙增韧材料的研究[J].pdfVIP

1 塑 料 2009年 38卷 第1期 张玉梅等——uHMwPE粉末作为MC铸型尼龙增韧材料的研究 UHMWPE粉末作为MC铸型尼龙增韧材料的研究 张玉梅，吴向阳，洪 尉，张 炜 (上海化工研究院，上海 200062) 摘要：研究了UHMWPE作为增韧材料对MC铸型尼龙力学性能和耐磨性的影响。接枝后的UHMWPE经环氧树 脂处理，填充到MC铸型尼龙体系中，当UHMWPE添加量为8％时，使 MC铸型尼龙冲击强度达到最大值，冲击强度 提高200％，磨损量降低6O％，降低5O％。冲击断面SEM照片分析结果表明：UHMWPE在MC铸型尼龙中能够均匀 分散，并在断面变得较为粗糙，呈现韧性断裂的特征。 关键词：UHMWPE；MC尼龙；增韧；环氧树脂；磨损量；摩擦因数 中图分类号：TQ325．12。TQ323．6 文献标识码：A 文章编号：1001—9456(2009)01—0068—03 Toughening Properties of MC Nylon with UHMWPE Particle ZHANG Yu-mei，WU Xiang—yang，HONG Wei，ZHANG Wei (Shanghai Research Institute of Chemical Indust~，Shanghai 200062，China) Abstract：It was focued on the influence of UHMWPE particle as toughening material on the mechanical and wear properties of MC nylon．Graft UHMWPE was treated by epoxy resin and then added to MC nylon as filler to prove its mechanical and wear properties．When the content of UHMWPE was 8％ ．the impact property of the composite was the best．The impact strength improved about 200％ ，the wear abrasion decreased about 60％ ．and the friction coefficient decreased 50％．The results showed that the mechanism of UHMWPE improving MC nylon was discussed by SEM photograph．The homogeneous dispersion of the modified UHMWPE in the MC nylon and surface roughness were remarkably proved the tenacity rupture’S character． Key words：UHMWPE；MC nylon；toughening；epoxy resin；wear abrasion；friction coefficient MC(Monomer Casting)尼龙，也称浇铸尼龙(又称铸型尼 减摩、增强、增韧等方面对MC尼龙改性研究比较活跃 。 龙)。浇铸尼龙是在阴离子催化剂及活化剂存在下，己内酰胺 增韧改性的常见方法是通过改变聚合物形态相结构进行物 单体直接浇铸于模具中聚合成型制得的。由于其生产工艺过程 理改性。与物理改性不同，化学改性从改变铸型尼龙化学结构 短，工艺