Orientation variation along growth direction of millimeter free-standing CVD diamond thinned by mechanical grinding.pdfVIP
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Orientation variation along growth direction of millimeter free-standing CVD diamond thinned by mechanical grinding.pdf
InternationalJournalofMinerals,MetallurgyandMaterials
Volum e21,Number8,August2014,Page839
DOh 10.1O07/s12613-014.0979-5
Orientationvariationalonggrowthdirectionofmillimeterfree-standingCVD
diamondthinnedbymechanicalgrinding
Xing-kaiWen,Jun-junWei, 一longLiu,Jian—ehaoGuo,Liang-xianChen,andCheng-mingLi
InstituteofAdvancedMaterialsandTechnology,UniversityofScienceandTechnologyBeijing,Beijing100083,China
(Received:29October2013;revised:19March2014;accepted:21March2014)
Abstract:A flee.standingdiamondfilm withmillimeterthicknesspreparedbvDCarcplasmajetwashtinnedsuccessivelybymechanical
grinding.Theorientationandqualityofhtedima ondfilmswim differenthtickn esseswerechraacterizedbyX—raydiffractionandRanaan
spectroscopy.respectively.111eresultsshow arandom grain-orientationdistributionduringtheinitialgrowthstage.Ashtefilm thicknessi11.
creases,thepreferredorientationofhtedima ondfilm chnagesfrom (111to(220).duetothecompetitivegrowthmechanism.Twinnnig
generatedduringthenucleationstageapperastosatbilizehtepreferentialgrowthalonghte110direction.111einterplanarspacingofthe
(220)plnaeisenlargedasthefilmthicknessincreases.whichiscausedbythenicreaseofnondiamond-phasecarbonandimpuritiesunder
htecyclicgas.Inaddition htequalityofhtediamondfilm isbraelydegradedduringhtergowthprocess.Furthermore,htepeakshiftdemon—
stratesasignificantinhomogeneityofstressalongthefilm growthdirection.whichresultsfrom competitivegrowth.
Keywords:dima ondfiml s;chemicalvapordeposition;grinding;orientation;rgowt hmechanisms;quality
ity distribution from hte nucleation surface to ultimate
1.Introduetion growthsurface.
Inthisstudy.tochraacterizetheorienattionandqualiyt of
Diamondisauniquematerial,whichshowsthehighest diamondfilmsduringhtegrowthprocess,X—raydiffraction
ha
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