阻燃硬质聚氨酯泡沫塑料产烟行为比较的研究.pdfVIP

阻燃硬质聚氨酯泡沫塑料产烟行为比较研究 谢松明1，杜建新1，郝建薇1，王希安2 1.北京理工大学材料学院，阻燃材料研究国家专业实验室，火安全材料与技术教育部1程研究中心，北京，100081 2.山东华德隆建材科技有限公司 莱州261400 将磷酸三 （β-氯异丙基）酯(TCPP)与甲基膦酸二甲酯(DMMP)分别用于改性过的可膨胀石墨(MEG) 阻燃硬质聚氨酯泡沫塑料(RPUF/MEG)中。采用建材烟密度测试仪研究了TCPP及DMPP磷含量、添加量对阻燃RPUF 最大烟密度及烟密度等级的影响。在此基础上，比较了硼酸锌(ZB)与蒙脱土(MMT)在添加了TCPP的RPUF/MEG 试样中产烟行为的差异。研究表明，DMMP用于RPUF/MEG复配体系中的产烟量较TCPP小；在RPUF/MEG-TCPP复 配体系中，ZB与MMT比较，前者的抑烟效果相对较好。 硬质聚氨酯泡沫塑料；阻燃；抑烟 A COMPARATIVE STUDY ON THEFIRE SMOKE PRODUCTION BEHAVIOR FORFLAMERETARDANTRIGIDPOLYURETHANEFOAMS XIESongming1,DUJianxin1,HAOJianwei1,WANGXian2 1NationalLaboratoryofFlameRetardantMaterials,EngineeringResearchCenterofFire-SafeMaterialsandTechnology,Ministryof Education,BeijingInstituteofTechnology,Beijing100081NationalLaboratoryofFlameRetardantMaterials,SchoolofMaterials,Beijing InstituteofTechnology,Beijing100081 2HuaDeLongBuildingMaterialTechnologyCo.,Ltd.,Laizhou,261400 Tris(elorisopropyl)phosphate(TCPP)anddimethylmethylphosphonate(DMMP)wasaddedtoflame retardantrigidpolyurethanefoams(RPUF)withmodifiedexpandablegraphite(MEG).Theimpactofthe phosphoruscontentandadditionofTCPPandDMMPonthemaximumsmokedensityandsmokedensityrating forflameretardantRPUFwasstudiedbytheapproachofbuildingmaterialssmokedensitytestinstrument.Based onthis,thedifferenceinthefiresmokeproductionbehaviorbetweenzincborate(ZB)andmontmorillonite(MMT) inRPUF/MEGwithTCPPwascompared.ComparedtoTCPP,DMMPhadlowerfiresmokeproductionwhen addedtoRPUF/MEGsystem.ZBshowedbetterfiresmokesuppressioneffectthanMMTinRPUF/MEG-TCPP system. rigidpolyurethanefoams(RPUF)； flameretardant； firesmokesuppression