基于柱[n]芳烃（准）轮烷的研究进展有机化学.pdfVIP

DOI: 10.6023/cjoc201312018 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 基于柱[n]芳烃(准)轮烷的研究进展 吴 旋a 段群鹏a,b 倪梦飞a 胡晓玉*,a 王乐勇*,a a ( 超分子化学与智能材料实验室 南京大学化学化工学院 南京 210093) (b 河南工程学院材料与化学工程系 郑州 450007) 摘要 柱芳烃作为一类新型的大环主体分子, 自2008 年首次报道以来, 引起了人们, 特别是化学家的广泛关注. 目前, 它已在分子识别、(准)轮烷、超分子聚合物、分子弹簧、智能跨膜离子通道、囊泡、金属有机骨架结构等众多研究领 域作为重要模块得到初步的应用. 主要将以柱芳烃作为主体大环分子来构筑(准)轮烷的研究进展进行简要的综述, 同 时还介绍了基于柱芳烃的(准)聚轮烷的研究概况, 并对未来的发展作了进一步展望. 关键词 柱[n]芳烃; (准)轮烷; (准)聚轮烷 Recent Advances of (Pseudo) Rotaxanes Constructed by Pillar[n]arenes Wu, Xuana Duan, Qunpenga,b Ni, Mengfeia Hu, Xiaoyu*,a Wang, Leyong*,a a ( Laboratory for Supramolecular Chemistry and Dynamic Materials, School of Chemistry and Chemical Engineering, Nanjing Universty , Nanjing 210093) b ( Department of Materials and Chemical Engineering, Henan Institute of Engineering, Zhengzhou 450007) Abstract Pillar[n]arenes, as a new generation of macrocyclic host molecules, have attracted widely attention since their dis- covery in 2008. They have been applied in the field of molecule recognition, rotaxanes, supramolecular polymers, molecular springs, artificial transmembrane channels, vesicles, and metal-organic frameworks (MOFs). In this review, the recent ad- vances of (pseudo)rotaxanes constructed by pillar[n]a