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Simple and Efficient Synthesis of Gold Nanoclusters and Their Performance as Solid Contact of Ion Selective Electrode.pdf

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Simple and Efficient Synthesis of Gold Nanoclusters and Their Performance as Solid Contact of Ion Selective Electrode.pdf

Electrochimica Acta 222 (2016) 1007–1012 Contents lists available at ScienceDirect Electrochimica Acta journal homepage: /locate/electacta Simple and Ef?cient Synthesis of Gold Nanoclusters and Their Performance as Solid Contact of Ion Selective Electrode Jianan Xua,b, Fei Jiac, Fenghua Lia,*, Qingbo Ana,b, Shiyu Gana, Qixian Zhanga, Ari Ivaskad, Li Niua,d,* a State Key Laboratory of Electroanalytical Chemistry, c/o Engineering Laboratory for Modern Analytical Techniques, CAS Center for Excellence in Nanoscience, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China b University of Chinese Academy of Sciences, Beijing 100039, PR China c School of Chemical Engineering, Changchun University of Technology, Changchun 130012, PR China d Laboratory of Analytical Chemistry, Johan Gadolin Process Chemistry Centre, ?bo Akademi University, FIN-20500?bo-Turku, Finland ARTICLE INFO Article history: Received 18 July 2016 Received in revised form 21 October 2016 Accepted 11 November 2016 Available online 13 November 2016 Keywords: Gold nanocluster one-phase method ion selective electrode solid contact transducer ABSTRACT Gold nanoclusters are ideal materials as solid transducer in all-solid-state ion-selective electrodes (ISEs) due to their high hydrophobicity, excellent ion-to-electron transduction, high speci?c capacitance and outstanding chemical stability. In this paper, monolayer-protected gold nanoclusters (MPCs) were synthesized by a simple one-phase method requiring a relatively short reaction time with high yield (60%). Transmittance electronic microscopy (TEM) and atomic-force microscopy (AFM) were used to characterize the morphology of MPCs. The composition of MPCs was studied by UV–vis spectrometry, Matrix-assisted laser desorption ionization (MALDI) mass spectrometry, X-ray diffraction (XRD) measurement and X-ray photoelectron spectroscopy (XPS) measurements. The performance of MPCs based ISEs was thoroughly characterized b