High Performance Liquid Chromatography inductively coupled plasma mass spectrometry determination of chemical forms of arsenic in dried seafood.docVIP

 PAGE \* MERGEFORMAT 16 High Performance Liquid Chromatography inductively coupled plasma mass spectrometry determination of chemical forms of arsenic in dried seafood Study: High-Wang Yang Cao Xuan Yu Jingjing Li Xianchun, such as [Abstract] high performance liquid chromatography inductively coupled plasma mass spectrometry studies of the kelp, Sargassum, such as dried seaweed and seagrass in seafood and chemical forms of arsenic. Experiments show that the major arsenic in dried seafood form of arsenic is unknown 3, unknown to the 3 arsenic were studied. by high performance liquid chromatography time of flight mass spectrometry of Sargassum and kelp in the three kinds of unknown molecular weight of arsenic, respectively, 329.0599, 483.0738 and 409.0162, by contrast, to determine the three unknown peaks were three kinds of arsenic carbohydrate: DMA glycerol ribose, DMA phosphate ribose and DMA sulfate ribose. on quantitative analysis of the samples showed arsenic, total arsenic in dried seafood Although the excess of the amount of GB limit on arsenic standards for seafood more than 20 times, but most of the major plant dry seafood arsenic speciation of arsenic is less toxic carbohydrate DMA sulfate ribose (U4, its content is about the amount of total extractable arsenic 51.1% ~ 80.3%, mainly arsenic in kelp DMA phosphate ribose (U3 in the form, accounting for 48.9% of arsenic can be extracted. [Key Words] high performance liquid chromatography, inductively coupled plasma mass spectrometry, time of flight mass spectrometry, arsenic, dried seafood, arsenic sugar 1 Introduction Seafood and dried seafood toxic elements in the relatively high consumption of arsenic endanger the health of [1 ~ 3]. Seafood arsenic has been found in nature as many as 25 species, and a variety of side effects of arsenic closely related to its morphology [4,5]. Among them, inorganic arsenic (As  and As  including the most toxic, organic form of a methyl arsenate (MMA,