Cellulose Acetate Sulfate as a Lyotropic Liquid Crystalline Polyelectrolyte Synthesis, Properties, and Application英文文献资料.docVIP
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Cellulose Acetate Sulfate as a Lyotropic Liquid Crystalline Polyelectrolyte Synthesis, Properties, and Application英文文献资料
HindawiPublishingCorporation
InternationalJournalofPolymerScience
Volume2010,ArticleID831658,17pages
doi:10.1155/2010/831658
ResearchArticle
CelluloseAcetateSulfateasaLyotropicLiquidCrystalline
Polyelectrolyte:Synthesis,Properties,andApplication
D.D.Grinshpan, S.E.Makarevich,
1T.A.Savitskaya,1,2N.G.Tsygankova,1 1
S.M.Tretsiakova, andT.N.Nevar
3 1
1
2
3
ResearchInstituteofPhysicalandChemicalProblems,BelarusianStateUniversity,LeningradskayaStreet,14,220030Minsk,Belarus
ScienceChemistryDepartment,BelarusianStateUniversity,LeningradskayaStreet,14,220030Minsk,Belarus
TheBuiltEnvironmentResearchInstitute,SchooloftheBuiltEnvironment,UniversityofUlster,Newtownabbey,BT370QB,UK
CorrespondenceshouldbeaddressedtoT.A.Savitskaya,savitskayata@bsu.by
Received13July2010;Accepted14November2010
AcademicEditor:RobertShanks
Copyright?2010D.D.Grinshpanetal. This is an open access article distributed under the Creative Commons Attribution
License,whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperly
cited.
The optimal conditions of cellulose acetate sulfate (CAS) homogeneous synthesis with the yield of 94–98wt.% have been
determined.CASwascon?rmedtohaveanevendistributionoffunctionalgroupsalongthepolymerchain.Thepolymerwas
characterizedbyanexceptionallyhighwatersolubility(upto70wt.%).Theisothermaldiagramsofitssolubilityinwater-alcohol
mediahavebeenobtained.CASaqueoussolutionsstability,electrolytic,thermal,andviscouspropertieshavebeende?ned.The
mainhydrodynamiccharacteristicssuchasintrinsicviscosity,Hugginsconstant,andcrossoverconcentrationhavebeenevaluated.
Theparametersofpolymerchainthermodynamicrigidityhavebeencalculated.Theformationofliquidcrystallinestructures
inconcentratedCASsolutionshasbeencon?rmed.CASwasrecommendedtobeusedasabinderforthemedicinalformsof
activatedcarbonandcarbonsorbentforwatertreatment,hydrophilicointmentfoundation.
1.Introduction
not been studied so
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