农业废弃物再生吸附剂制备及其性能的研究.docxVIP

剂，经过真空烧结制备了茭白叶混合吸附剂。设计进行了不同吸附条 件下的吸附实验，研究了吸附剂吸附磷元素的行为。研究结果发现： 采用 0.1mol/LCaCl2 以及 1mol/L K2CO3 溶液浸渍茭白叶，烧结制备的混 合吸附剂，在吸附剂用量为 0.1g，吸附时间为 32 小时的实验条件下， 被吸附后的水溶液磷元素含量可达地表水环境质量标准 （GB3838-2002）一类湖库水质标准总磷含量为 0.02mg/L(ppm)以下。 利用 X 射线衍射揭示了茭白叶混合吸附剂中存在碳酸钙微晶是吸附去 磷的主要原因。上述混合吸附剂经酸洗和氯化铁溶液浸渍处理，针对 实际湖水样品进行了磷吸附实证研究，取得了较好的效果。 关键词：农业废弃物，茭白叶，富营养化，吸附剂，吸附去磷，活性 炭 ii Research on the preparation and property of bio-sorbent made from agricultural residues Abstract This paper aims at dealing with the eutrophic water caused by the excessive phosphorus nutrient in the industrial detergents and agricultural fertilizers. The bio-sorbent I—the cellulosic material Water Bamboo Leaves (WBL) treated with FeCl3 solution is found to improve the phosphorus removal capability. The adsorption results show that the bio-sorbent has much greater phosphorus removal capacity than natural WBL. By studying the effects of the different experimental parameters, the best phosphorus removal capacity could achieve 4.36mg/g at the conditions of the pieces size WBL modified with 5%FeCl3、pH at 5.5、the time of the adsorption at 30h. Through the Infrared spectra, we study the adsorption mechanism. In this paper, the bio-sorbent II—the cellulosic material Water Bamboo Leaves (WBL) treated with FeCl2 solution is taken for research about its phosphorus removal capability. Through the SEM, we found the surface morphology changes between WBL and the bio-sorbent. By studying the effects of the different experimental parameters, the best phosphorus removal capacity could achieve 5.02mg/g at the condition of the pieces size WBL modified with 12%FeCl2、pH at 5.5、the time of the adsorption 30h. The high phosphorus removal capacity mechanism could be due to the formation of compounds on the bio-sorbent. The compounds formed through the ferric ions reacting with hydroxyl on the WBL cellulose. Kinetics studies revealed that the adsorption process follows a pseudo-first order kinetic mode. Using 0.1mol/LCaCl2, 1mol/L K2CO3 as Catalyst an