功能化碳纳米管与四苯基锌卟啉轴向配位组装.pdfVIP

第 26卷第 11期 无 机 化 学 学 报 Vo1．26No．1l 2010年 11月 CHINESEJOURNALOFINORGANICCHEMISTRY 1939—1943 功能化碳纳米管与四苯基锌卟啉轴向配位组装 佟履冰 姜 李 孙 剑 尹 桂 南京 2100931 (南京大学化学化工学院， 摘要 ：本文报道了一种基于四苯基锌卟啉与含吡啶基功能化多壁碳纳米管经轴 向配位组装 。它们被红外光谱 、拉曼光谱和透射 电镜所表征。荧光光谱研究表 明，在该体系中功能化多壁碳纳米管能有效地淬灭卟啉的荧光。 关键词 ：多壁碳纳米管 ；卟啉 ；轴 向配位 ；荧光 中图分类号：0613．71 文献标识码：A 文章编号：1001—4861(2010)11-1939—05 SupramolecularSelf-assemblyofZincTetraphenylpOrphyrinwithFunctionalized Multi．walledCarbonNanotubesviaAxialCoordination TONGLU—Bing JIANG Li SUNJian YINGui (SchoolofChem~tryandChemicalEngineering,NanjingUniversity,Nanjing210093) Abstract：Functionalizedmulti—walledcarbonnanotubes (MWCNTs)containingpyridylgroupwerepreparedand characterizedbyFouriertransform—infraredspectra，Raman spectraandtransmission electronmicroscope．The interaction between the functionalized MWCNTs and zinc tetraphenylporphyrin via axialcoordination was investigated byUV—Visand fluorescence emission spectra．MWCNTscan effectively quench fluorescence of ZnTPPviaaxialcoordination． Keywords：multi—walledcarbonnanotubes；zinctetraphenylporphyrin；axialcoordination；fluorescence Sincethediscoveryofcarbonnanotubes(CNTs)in dyeswith alargeextinction coe±licientin thevisible 1991 theyhaveattractedmuchattentionbecauseof lightregion，have predictable rigid structures，and theirremarkable optical，electrical，and mechanical possess prospective photochemical electron-transfer propertiesandpotentialapplicationsinvariousfields ability， and extensively used in self-assembling includingnanodevices，fieldeffecttransistors，full—color processestopreparemonolayerand muhilayerfilms displays，sensors，uhra