水力造粒-微滤组合工艺处理模拟含锶放射性废水.pdfVIP

ABSTRACT A prilling method was investigated through hydraulic stirring in order to solve the increasing management difficults of mechanical equipment and radiation protection in mechanical mixing prilling-microfiltration combination process which has a good effect on strontium removal. The strontium element was removed by forming compacted crystal particles when Na CO and CaCO were used as precipitating agent 2 3 3 and crystal seed, respectively. In order to improve the settling effect and reduce membrane fouling, flocculant FeCl3 was dosed in the membrane separator with concentration of 10 mg/L.The sedimentation performance of the particles formed by prilling was improved and the effluent turbidity was reduced so that the load of following microfiltration process was alleviated. The hydraulic mixing prilling-microfiltration combination process for strontium removal is divided into the seed crystal-preparation stage and the strontium-removal stage. In the seed crystal-preparation stage, the results showed that the formed crystal particles were compacted after 30 prilling cycles. The mean removal rate of hardness was 55% and the turbidity was under 0.50 NTU in the precipitated effluent . Practical size became bigger and centralized in distribution with the operation, the average size of crystal particles that obtained was 49.10 μm. The crystal seed particle size was large enough with good settleability to meet the requirements of the later strontium-removal stage. The later study found that lower prilling efficiency became a bottleneck of experiments of high crystal seed dosing quantity in strontium-removal stage. So the research changed CaCO3 dosing quantity