贵阳市耕地土壤中有效态Cd提取条件及其含量分析研究.pdfVIP

安徽农业科学。Journal ofAnhui A ．Sci．20O7。35(36)：11923—11925 责任编辑 孙红忠 责任校对 李洪 贵阳市耕地土壤中有效态Cd提取条件及其含量分析研究 吉玉碧 ，谢锋2，谭红 ， ，何锦林2，陆洋2，邓秋静2 (1．贵州省复合改性聚合物材料工程技术研究中心，贵州贵阳550014；2．贵州省理化测试分析研究中心，贵州贵阳550002) 摘要 通过采用不同土液比、提取剂及浓度等，利用L／Y)正交表设计提取工况，分析各工况对土壤有效态cd提取量的影响，及提取量 与土壤主要理化性状的相关关系，提出以20目土样1．0 g，加入0．1mot／L Caa2提取剂5 rTll，在温度(2O±5) ℃振荡1．5 h后的检测值表示 贵阳市耕地土壤中有效态cd含量较为合适。最佳提取工况实验条件下，贵阳市耕地土壤有效态cd提取率范围是4．o4％ 18．99％，均 值为9． ％，初步表明其所种植作物受cd污染的风险并不大。修文县土壤有效态cd提取率为最大值l8．99％，白云区土壤总cd与有 效态cd相关系数为最大值0．870，呈明显正相关，其余地区相关性均不显著。有效态cd提取率随pH值的升高而降低，在pH值5．5～ 6．5，总cd与有效态cd之间的相关系数为最大值0．860，呈明显正相关。 关键词 土壤；CA；有效态；提取条件；贵阳 中图分类号 S153．1 文献标识码 A 文章编号 0517—66l1(2OO7)36—11923—03 Study 811 tlle D血丑c血 Condition for Available CA and Content in Cultivated S0il of Guiyang City JIYu．bi et al (C~izhouB nee血1gResearch Centerfor Corr~poundM0d ed PolymerMaterials，Guiyang，Guizhou 550014) Abs t n1e available CA in soil WaS extracted in different conditions oforthogonal table (34)，which contained different extract solvent，concentration and ratio of soil to solvent and 80 on．，Il extracting efficiency in di虢rent extracting condition and the correlation between extracting efficiency and its physical and chemical properties in soil were studied．1he best extract condition for available CA in cultivated soll of Guiyang City WOS 1．0 g so．1 sample with 5 ml 0．1 mol／L CaC12 extract solvent at(20±5)oC，1．5 h．At the best extract condition，the extracting ettlciency scope of available CA in Guiyang culti．vated soilwas4．04％～l8．99％，the nleaI1was9．22％．It showedthatthe risk ofbe poUuted byCdto cropswasD’t seHous．In addition，theIl1a)(． imum ofavailable CA extracting efficiency was l8．99％ in Xiuwen County．Cd and available CA in cultivated soi was significantly correlated in Baiyun Dis． ct．the correlation coefficient was 0．87．111e extraction efflcieney ofavailable CA decreased wit}l pH increased．Cd and available CA in cultivated soi was signiilcanfly correlated whe