热解及燃烧过程中燃料氮的N2转化特性.pdfVIP

第42卷 第3期 西 安 交 通 大 学 学 报 Vo1．42 №3 2OO8年3月 JOURNAL OF XI AN JIAOTONG UNIVERSITY Mar． 2008 热解及燃烧过程中燃料氮的N2转化特性 刘海峰，刘银河，刘艳华，车得福 (西安交通大学能源与动力工程学院，710049，西安) 摘要：利用气相色谱设备实验研究了国内4种煤在热解及燃烧过程中煤中燃料氮向Nz的转化特 性．研究结果表明：在煤的热解过程中，燃料氮能够转化为Nz，煤种不同，Nz的转化率也不同；神木 煤氮的N 转化率最高，焦作煤最低；随热解温度的升高，燃料氮的Nz转化率升高；在煤燃烧过程 中，燃料氮同样能够转化为对环境无害的Nz，转化率同样与温度有关且随着温度的升高而增加，但 当燃烧温度达到1 100℃时，除神木煤外，其他煤中燃料氮的Nz转化率均有明显下降；无论是热解 还是燃烧，所研究煤中的矿物质均能够促进燃料氮向Nz的转化；无论脱灰与否，低温燃烧时燃料 氮的N 转化率远比低温热解时高，但在1 100℃下的热解与燃烧时，Nz转化率与煤种有关． 关键词：N2转化率；热解；煤燃烧；燃料氮 中图分类号：X131．1 文献标志码：A 文章编号：0253—987X(2008)03—0350—04 N2 Formation from Coal Nitrogen During Pyrolysis and Combustion LIU Haifeng，LIU Yinhe，LIU Yanhua，CHE Defu (School of Energy and Power Engineering．Xi an Jiaotong University，Xi an 710049，China) Abstract：Four kinds of native coals were applied to investigate for N2 formation from coal nitro— gen during pyrolysis or combustion with a gas chromatographic analysis system．The experimen— tal results show that a part of coal nitrogen can be converted into N2 during pyrolysis．The per— centage of N2 formation from fuel nitrogen is highest for Shenmu and lowest for Jiaozuo coa1．N2 formation percentage formed increases with the increase of temperature．During coal combustion， N2 can also be formed from coal nitrogen，and N2 formation percentage also depends on tempera— ture．The percentage of N2 formation from coal nitrogen increases with temperature at the tem— perature lower than or equal to 900℃ for the coals studied while it decreases obviously at 1 100 ℃ except Shenmu coa1．The minerals in the coals studied can enhance the N2 formation whether during pyrolysis or during combustion process．The percentage of N2 formation during low tem— perature combustion is