马拉硫磷在黄瓜中的残留降解动态.pdfVIP

第8 卷 第3 期 现 代 农 药 Vol.8 No.3 2009 年6 月 Modern Agrochemicals Jun. 2009 马拉硫磷在黄瓜中的残留降解动态 李培征，陈文佳，骆焱平* （海南大学环境与植物保护学院，海南儋州 571737 ） 摘要：建立了黄瓜中马拉硫磷气相色谱检测方法。样品用乙腈提取，丙酮定容，样品采用外标 法定量。结果表明，仪器对马拉硫磷最小检出量为0.002 ng ，在添加浓度为0.002～0.100 mg/kg 时，回收率为93.6%～111.7%，相对标准偏差为2.8% ～20.8% 。马拉硫磷在黄瓜上降解很快，半 衰期0.35 d ，施药后3 d 其残留量已低于仪器检出限。 关键词：黄瓜；马拉硫磷；残留 中图分类号：TQ 450.2＋63 文献标识码：A doi ：10.3969/j.issn.1671-5284.2009.03.012 Residual Degradation Dynamics of Malathion in Cucumber LI Pei-zheng, CHEN Wen-jia, LUO Yan-ping* (College of Environment and Plant Protection, Hainan University, Hainan Danzhou 571737, China) Abstract: A gas chromatographic (GC with FPD) method for the determination of malathion in cucumber was developed. Malathion in cucumber was extracted by acetonitrile, the residue was redissolved with acetone, and malathion was quantified by external standard method. The result showed that the limit of detection was 0.002 ng ，the recoveries were 93.6% to 111.7% when the added levels were from 0.002 to 0.100mg/kg, the RSD was 2.8% to 20.8%. Malathion degraded rapidly and the half-life of malathion in cucumber was 0.35 day, the residue of malathion was lower than the limit of detection three days later. Key words: cucumber; malathion ; residue 马拉硫磷 (malathion) ，又名马拉松，属低毒低 个重复和 1 个空白对照。在花期黄瓜生长至半大时， 残留的有机磷杀虫剂，有良好的触杀和一定的熏蒸 以20%高氯·马热雾剂2.85 L/hm2 的剂量施药。按照 作用，主要用来防治粮食、棉花和蔬菜等作物的多 随机取样原则，于施药后 1 h、6 h、12 h、1.5 d、2 d、 种害虫[1] 。目前关于马拉硫磷残留研究的报道主要 3 d、5 d、7 d、9 d 采样,每次随机采摘 6～8 条黄瓜[4] 。 为花生及粮食作物上[2-3] 。为评价马拉硫磷在蔬菜上 1.3 分析方法 的安全性，