等离子喷涂制备Al2O3ZrO2复合结构热障涂层的性能.docVIP

等离子喷涂制备A12O3/ZrO2复合结构 热障涂层的性能 杨宏波刘朝辉易童彬刘娜舒心罗平 工业第五九研宄所 以NiCrAlY为金属黏结层材料、以A12O3和ZrO2*陶瓷层材料，采用等离子喷涂 技术在304不锈钢表面制备了 3种热障涂层，通过扫描电子显微镜（SEM）和X 射线衍射仪（XRD）分别对涂层的微观形貌和晶相进行了表征，并研宄了涂层的 抗高温氧化性能和抗热震性能。结果表明:NiCrAlY/Al203/Zr02复合结构热障涂层 表而无孔洞和裂纹等缺陷，高温氧化后该涂层主要包括Mg2Zr50l2ff （Fe，Mg） （Cr, Ee） 20,两种晶相；由于A1A的阻氧作用，NiCrAlY/Ah（VZrO2涂层具有最佳 的抗高温氧化性能;NiCrAlY/ZrO2涂层层间材料的热膨胀系数呈梯度变化，表现 出最佳的抗热震性能。 关键词： 等离子喷涂;热障涂层;抗高温氧化性能;抗热震性能; 杨宏波（1990-）,男，湖北黄M人，研究生 刘朝辉教授 2017-05-24 基金：重庆市研宂生科研创新项FI （CYS16238） Properties of A1203/Zr02 Composite Structural Thermal Barrier Coating Prepared by Plasma Spraying Method YANG Hongbo LlUZhaohui YI Tongbin LIUNa SHU Xin LUO Ping Department of Military Facility, ALUP; No. 59 Institute of China Weapons Industry; Abstract： Three kinds of thermal barrier coating were prepared on the surface of 304 stainless steel by plasma spraying method with NiCrAlY served as metal bonding layer material and Al203 and ZrO2 served as the ceramic layer materials. The microscopic morphology and crystalline phase of the coating was characterized by scanning electron microscope (SRM) and X-ray diffractometer (XRD) . The high temperature oxidation resistance and thermal shock resistance of the coating were also studied. The results show that NiCrA1Y/Al203/Zr02 composite structural thermal barrier coating surface did not have any hole and crack, and there were Mg2Zr50|2 and (Fe, Mg) (Cr, Fe204 crystal 1ine phase in the coating after high temperature oxidation. NiCrAlY/ZrO2 coating had the best high temperature oxidation resistance because of the oxygen barrier effect of Al203. The thermal expansion coefficient of interlayer material in NiCrAlY/ZrO2 coating had a gradient trend and the coating exhibited the best thermal shock resistance. Keyword： plasma spraying; thermal barrier coating; high temperature oxidation resistance; thermal shock resistance; Received： 2017-05?4 0引言 热障涂层(TBCs)是指由MCrAlY (M为Co, Cr或Co+Cr)金属黏结层和陶瓷面 层组成的复合结构涂层，主要用于对燃气轮机、涡轮发动机等高温零部件的表面 进行热防护。在高温氧化环境中，环境中的氧元素通过涂层中的毛细通道侵入黏 结层与陶瓷面层的界