近红外光谱法快速测定白酒中的酒精度.pdfVIP

中国农学通报 2010,26(19):70-72 Chinese Agricultural Science Bulletin 近红外光谱法快速测定白酒中的酒精度 1 2 1 2 徐 玮 ，谭 红 ，包 娜 ，何锦林 1 2 （贵州大学，贵阳550002；贵州省理化测试分析研究中心，贵阳550002） 摘 要：为了得到白酒工业中酒精度的快速检测技术。将偏最小二乘法与傅立叶变换近红外光谱法相结 合，建立白酒酒精度的快速定量模型。通过标准归一化预处理光谱，光谱范围选择5731.40~5897.25、 5901.11~6063.10、8327.12~8423.54 cm-1 ，主成分数为5，得到模型的内部交互验证相关系数(R)为0.9992， 交互验证均方差(RMSECV) 为0.263；模型的预测值与实测值的相关系数为0.99，预测标准偏差(RMSEP) 为0.435。结果表明，模型的预测效果很好，具有较高的精密度和良好的稳定性，能满足生产中白酒酒精 度的快速检测要求。 关键词：近红外光谱法；快速；白酒；酒精度 中图分类号：O657.33 文献标志码：A 论文编号：2010-1235 Rapid Determination of Alcohol Content in Distilled Spirit by NIR Spectroscopy 1 2 1 2 Xu Wei , Tan Hong , Bao Na , He Jinlin 1 2 （Guizhou University, GuiYang 550002; GuiZhou Research Center of Physical Test And Chemical Analysis, GuiYang 550002） Abstract: In order to measuring alcohol concentration in distilled spirit accurately and quickly, a calibration model was established based on Fourier Transform Near Infrared Spectroscopy with partial least square. According to the selected spectra ranges of 5731.40-5897.25, 5901.11-6063.10, 8327.12-8423.54 cm-1 and standard normal variate processing method, the rank was five. The correlation coefficient(R) of the model and the root mean square error of cross validation (RMSECV) are 0.99916, 0.263 respectively, Then the model was tested and evaluated and the result showed the R of the test set and the root mean square error of prediction (RMSEP) are 0.99,0.453 respectively. The method has been applied to qui