Chapter 5 The Schrodinger equation in three dimensions 量子力学英文教案教材.pptVIP

Chapter 5 The Schrodinger equation in three dimensions;§1 The Schrodinger Equation with a Central Potential;Hamilton;The solution of Schrodinger equation;Let;Wave function conditions;νmax = nr;β= n into recursion relation ：;The total wave function ：;Normalizable conditions for spherical function：;The first few of the radial wave function R n l are：;The eigenvalue and the eigenfunctions ; Home works Chapter 6 P131: 2, ;Two–body problem The energy levels and wave function The hydrogen-like atoms;?1;Hamilton ：;Dividing by ? (r) ? (R); n = 1 is ground state ， E1 = -(? e4 / 2 ?2 )， when n → ∞， E∞ = 0， The ionization energy is： ε= E∞- E1 = - E1 = μe4 / 2 ?2 = 13.579 eV.;（2）The wave function and the probability distribution;;[2，1];[3，2];3. The angular probability density distribution;Example 2. When ?=1, m=± 1，W1,±1(θ) = (3/8π)sin2 ?. ? = π/2， W1,±1(π/2) = (3/8π). When ? = 0, W1,±1 = 0;m = -2;The hydrogen-like atoms; Home works Chapter 6 P131: 6, 7