介孔硅球负载金属催化剂的制备及催化活性的分析-preparation of mesoporous silica sphere supported metal catalyst and analysis of its catalytic activity.docxVIP

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介孔硅球负载金属催化剂的制备及催化活性的分析-preparation of mesoporous silica sphere supported metal catalyst and analysis of its catalytic activity.docx

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介孔硅球负载金属催化剂的制备及催化活性的分析-preparation of mesoporous silica sphere supported metal catalyst and analysis of its catalytic activity

AbstractWeknowthatahomogeneouscatalystcanspeedupthereactionrate.Butitisdifficulttoisolatetheproductafterthereaction.Ithasundoubtedlyincreasedthedifficultyprocessing.Notonlythat,thecatalystcan’tberecycled.Thiswillresultinwasteofresourcesandenvironmentalpollutionandaseriesofissues.Heterogeneouscatalyst,inparticular,theemergenceofmesoporoussilicamaterialsgreatlyimprovethedrawbacksofthehomogeneouscatalyst.Theyareeasilyseparatedfromtheproduct.Itcanberecycledaslongasasimplecentrifugation.Supportedmesoporousmaterialisfarmorethanthetopoftheseadvantages.Theyalsohaveahighthermalandmechanicalstability.Synthesismethodsandprocessesissimpe.Onlyoneormoresiliconsourceisprovidedundercertainconditionscopolymerizationtemplatingagent.Thetemplateisremmovedthenmaterialsareacquired.Thecatalystismostlybasedonacovalentbondmaterialincorporatedinthesilicon.Sothat,thecatalystcanbeaverystrongbondtothematerial.Bycentrifugation,thecatalystisseparatedfromthereactionsystem.Thecatalystremainsboundtothematerial.So,thecatalystwilberecycled.Therearealotofsurfaceactivegroupssuchashydroxy.Thesereactivegroupscanbemodifiedandheircharacteristicscanbechanged.Wecangainthedesiredfunction.Synthesizedmesoporousmaterials,thereisaspecificmorphology,regularmesopores,adjustableapertureandaspecialsilicatecavities.Therearespecificconfinementeffect,thiseffectalsoenhancetheenantiomericstereoselectivitysomereactions.Typesofmesoporoussiliconmateriallot,accordingtothesiliconskeletonpoints,canbedividedintoinorganicskeleton,organicframework,organic-inorganiccompositeskeleton.Inviewofallaspectsoftheadvantagesoforganic-inorganiccompositeskeleton,weuseittosynthesizemesoporoussilicaballsupportedrutheniumcatalystsandmesoporoussilicabeadsloadedmetaliridiumcatalysts,andtestedtheiractivity.Synthesisofmesoporoussilicaballsupportedmetalrutheniumcatalystandasymmetrycatalysisresearch.InorganicsourceofsiliconTEOSandorganicsourceofsiliconecopolymer,CTACastemplate.GetTs-DPENfunctionalizedmesoporoussilicasphere.Thenthemetalrutheniumisadded.