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hpd100树脂对水中腐殖酸的吸附分析-adsorption analysis of hpd 100 resin on humic acid in water
AbstractNortheastbecauseofitsspecificclimateandgeologycharacteristics,thehigherhumicsubstancesinreservoirsourcewhichwerehardtoremove,aseriesofinfluenceemergedinmanylocalcitiestothewatersupplysafety.Inpresent,themainlyremovaltechnologiesforhumicsubstancesinwatermainlyincludethemembranefilter,theactivatedcarbonandbiodegradation,etc,however,theshortcomingsarehighcostandlowadsorptioncapacity.Therefore,tiisessentialtoseeksomeeconomicaladsorptionmaterialswithgoodselectivityandhighadsorpyionpropertiestoremovehumicsubstances.Inthisdissertation,theidealproduct-surfacemodifiedhypercrosslinkedmacroporousresinwithanimografted,wastoimprovetheadsorptionperformanceofadsorptionresins.Furthermore,thehumicsubstancesadsorptionpropertiesandmechanismsofthestntheticproductwerestudiedsystematicallywithhumicsubstancesasthetargetpollutants.Themaincontributionsareasfollows:Threekindsofmacroporousadsorptionresins（HPD100,HPD300andD-101）wasusedtomakestaticadsorptionexperiment.FoundthebestabsorbentHPD100withgoodadsorptioneffect.TheexperimentshowsthatthebiggeststaticadsorptionquantityofHPD100was1.52mg/gdryresinundertheconditionofnormaltemperatureandpHwas7.GraftaminoonthesurfaceofHPD100,usethetwokindsofresinstododynamicadsorptionexperimentanddynamicdesorptionexperiment.Thedynamicadsorptionexperimentresultsshowthat:theadsorptionquantityofthemodifiedmacroporousadsorptionresinwas1.85mg/mLin4BV/hvelocityandadsorptionratewas83.6%.Afterwarmingadsorptioneffectbecomespoor,heatingupgoagainsttheadsorption,itprovedthatmacroporousadsorptionresinhasaphysicaladsorptionproperties.Andthethermodynamicparametersoftheadsorptionmechanismresearchshowedthat:themodifiedmacroporousadsorptionresinhadbothphysicalabsorptionandchemicalabsorptioncharacteristics.Thedesorptionexperimentresultsshowthat:NaOHsolutionhasthebesteffect.EverytimethefreshNaoHsolutionareusedforresintodesorbanduesNaoHsolutioncircularly,theformeradsorptionratewashigherthanthelatter,theformerdesorptionratewashigherthanthelattertoo,theformeradsorptionrateca
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