分子印迹溶胶-凝胶材料的合成与应用分析-synthesis and application analysis of molecularly imprinted sol-gel materials.docxVIP

甲醇体系和水体系中对邻苯二甲酸酯的吸附性能进行表征，结果证明分子印迹溶胶－凝胶材料在对水中的邻苯二甲酸酯类环境激素吸附处理方面有良好的应用前景。 另外，目前对环境中雌激素类污染物的检测一般需要繁琐、耗时的样品预处理 过程，如液-液萃取等。本文以 DBP 分子印迹聚合物为敏感材料首次构建了分子印 迹-石英晶体微天平传感器，无须样品前处理，直接对水样中的邻苯二甲酸二丁酯进行检测。有望在环境检测和环境监测领域得到广泛的应用。 关键词：分子印迹，溶胶－凝胶，环境激素AbstractMolecular imprinting technique (MIT) is a technique for synthesizing polymers possessing specific recognition to target molecule. It is an attracting technique to mimic the function between antibody and antigen.The molecular imprinting polymers (MIPS) have a number of advantages including high strength, stability and long life. So, molecularly imprinted polymers (MIPs) are of growing interest for their potential applications as artificial enzymes, advanced materials for solid-phase extraction, and thin coatings for sensor devices.Sol–gel imprinting may be one progression. Sol –gel materials are inorganic (siloxane) based polymers formed by the acid or base catalysed hydrolysis and condensation of a series of silane monomers. Inclusion of a template species results in the formation of imprinted media. When the template was removed, MIPs produced a cavity with molecular recognition sites that could bind selectivity to the original template. Sol–gels are extremely versatile materials and have a wide area of application in analytical chemistry. Their optical transparency as well as chemical inertness, rigidity and porosity makes them ideally suited for use as optical sensing devices among other special applications. Their synthesis is straightforward and the availability of a range of pure functional monomers makes their use in molecular imprinting all the more attractive.Environmental hormones are stimulants in our living environments, which function as hormones, interfere with the normal secretory process in human body, lead to various negative biological effects and pose a threat to the health of human being and animals.Phthalate (such as di-n-butyl-phthalate), is a worldly organic pollution substance which is mass produced and w