元素替代和热处理对re-mg-ni基a2b7型贮氢合金的改性研究-modification of re - mg - ni based a2b7 hydrogen storage alloy by element substitution and heat treatment.docxVIP

theresidualphasewhichisAB5phase.Pr5Co19typephasedisappearsafterannealingtreatmentprolongedto9h.Moreover,theabundanceofA2B7phasedecreasewiththeincreasingoftvaluewhichisfrom6to12,buttheA5B19phaseandtheAB5phaseabundanceshowsthereversetrend.Themaximumdischargecapacityofalloyelectrodesincreasesfrom326.6mAhg-1(t=6h)to368.4mAhg-1(t=12h)withtheincreasingoftvaluebuttheHRD2000decreasesfrom63.8%(t=6h)to55.5%(t=12h),whichisdeterminedbythehydrogendiffusioncoefficient.Thecyclingcapacityretentionrateatthe200thcyclemonotonicallyincreasesfrom67.0%(t=6h)to70.6%(t=12h),whichshouldbeascribedtotheimprovementofcorrosionresistanceofalloyelectrodesinthecharging/dischargingcycle.Keywords:Re-Mg-Ni-basehydrogenstoragealloys；Ni/MHbattery；Heattreatment；Microstructure；Electrochemicalperformance目录摘要………………………………………………………………………………...IAbstract………………………………………………………………………………..II1绪论…………………………………….……………………………………………...11.1选题背景………………………………………………………………….………11.2贮氢合金概述…………………………………………………………………….21.2.1贮氢合金的基本性质………………………………………………………...21.2.2贮氢合金的研究现状……………………………..…………………………31.2.3贮氢合金的发展方向……………………………..….………………………41.3MH/Ni电池………………………………………………………………………51.3.1MH/Ni电池的原理…………………………………………………………...51.3.2MH/Ni电池的应用现状……………………………………………………...71.3.3MH/Ni电池的发展趋势……………………………………………………...71.4贮氢合金电极分类与研究现状…………………………………...……………...81.4.1AB5型贮氢合金…………………………………………………………81.4.2AB3型贮氢合金……………………………………………………………...91.4.3Re-Mg-Ni基贮氢合金……………………………………………………...101.5热处理在贮氢合金中的应用…………………………………………………...131.5.1热处理技术简介…………………………………………………….……...131.5.2热处理的应用………………………………………………………………131.5.3Re-Mg-Ni基A2B7型贮氢合金的热处理………………………………….141.6本文的研究内容………………………..……………………………………...142实验设备及过程……………………………………………………………………162.1实验设备和样品………………………………………………………………...162.1.1实验设备…………………………………………………………………..162.1.2实验样品………………………………………………………………...…162.2实验过程……………………………………………………………………….172.2.1贮氢合金的热处理………………………………………………………172.2.2贮氢合金电极片的制备………………………………………………….182.2.3贮氢合金结构分析……………………………………………………….192.2.4贮氢合金P-C-T曲线测试………………………………………………..202.2.5贮氢合金电化学性能的测试………………………………………………223Sm含量对La0.5Nd0.35-xS