磁场作用下制备煤系针状焦的性能分析-performance analysis of coal series needle coke prepared under magnetic field.docxVIP

太原理太原理工大学硕士研究生 学位论文STUDIES ON PROPERTIES OF COAL-SERIES NEEDLE COKE PREPARED IN MAGNETIC FIELDABSTRACTAs a new type of carbon materials，needle coke is applied to industrial， defense，energy，environmental protection and other fields based on its excellent comprehensive performance. At present ，it mainly used as skeleton materials of high power electrode and ultra high power electrode. Furthermore the researchon its application in lithium ion battery and super electrochemical capacitor obtained some achievements. In recent years，there is certain capacity interiorly， but the performance index is difficult to sati均 the demand of high powerelectrode.Therefore ，it is very important to study the inf1uence of various external factors during the carbonization ，which have important significance andpractical value in improving the comprehensive performance.Taking medium temperature coal tar pitch removed the QI as raw material， the needJe coke was made in a pressure vesseJ under the condition of exerting magnetic field. By changing the heating mode，heating rate，deJayed coking temperature，poJ归到erization pressure，the stage of carbonization when appliedmagnetic field and magnetic induction ，to research the influence of a11 factors in 由e process of prepa?ing needle coke comprehensively . The morphology and optical anisotropy organizations of needle coke were observed by ScannìngIII太原理工大学 硕士研究生学位论文Electron Microscope (SEM) and Polarizing Microscope，and the microcrystalline structure parameters was researched by X-Ray Dif仕actomer(XRD). The needlecokes prepared in different condition are made into work electrodes(WE) respectively.Then 由e capacitance characteristics ，reversibility and interface stability of WE was researched by CycIic Voltammetry(CV) and Electrochemical lmpedance Spectroscopy (EIS) in Three毛lectorde systemformed by needle coke electrode，platinum electrode(CE) and calomelelectrode(RE).Tbe conclusions ar