双偶氮基钳形钯ⅱ化合物的合成及其在sonogashira和suzuki反应中的催化应用-synthesis of disazo - based pincers palladium ii compound and its catalytic application in sonogashira and suzuki reactions.docxVIP

本文用到的缩写DMSO二甲基亚砜TBAB四丁基溴化铵TEA三乙胺THF四氢呋喃dba二亚苄基丙酮MLCT金属→配体电荷转移LLCT配体和配体之间的电荷转移TON产物的摩尔数与催化剂摩尔数之比目录第一章绪论..................................................................................................................11.1环金属反应的概述.................................................................................11.2钳形金属化合物的概述.........................................................................21.2.1钳形金属化合物的分类..............................................................31.2.2钳形金属化合物的合成方法......................................................41.3钳形钯化合物的催化应用.....................................................................72.1实验仪器与试剂...................................................................................212.1.1实验仪器与测试仪器................................................................212.1.2实验药品与试剂........................................................................212.1.3溶剂的处理................................................................................22dba的制备22Pd2(dba)3的制备222.1.6对溴苯乙酮的制备....................................................................222.1.7对氯苯甲酸乙酯的制备............................................................222.1.8苯乙炔的制备............................................................................232.1.9碘苯的制备................................................................................232.2化合物2a-2d,7,11的制备232.2.1实验步骤....................................................................................242.2.2产率及理化数据分析................................................................242.3化合物3a-3d,8,12的制备252.3.1实验步骤....................................................................................262.3.2产率及理化数据分析................................................................262.4共价型钯化物4a-4d的制备272.4.1实验步骤....................................................................................282.4.2产率及理化数据分析................................................................28-2.5NO3-,ClO4离子型钯化物的制备292.5.1实验步骤..................................