四种不同构架zno一维纳米材料制备及在量子点敏化太阳能电池中应用-preparation of zno one-dimensional nano-materials with four different frameworks and their application in quantum dot sensitized solar cells.docxVIP

ABSTRACTRecentlyquantumdot-sensitizedsolarcells(QDSCs)havebeenpaidattentionsbylotsofresearchersforitsgreatstablesensitizerwhichwouldnotbedecomposedwithtimeelapsing.One-dimensionalZnOnanomaterialsplayaveryimportantroleinsensitizedsolarcellsforitsrelativelyhighconductivitythatcanprovideaelectronicchanneldirectly.Inthisarticle,hydrothermalmethodwasemployed,andfourarchitecturesassembledbyonedimensionalZnOnanostructuresweresynthesisedthroughdifferentexperimentalparameter.AfterSLARprocessweobtainedacertainamountofCdSquantumdotslayer,andsystematicallystudiedtheperformancesofthesebasedsensitizedsolarcells.Themaincontentsarelistasfollows:①Use5mMzincacetatesolutionforbreeding,includingzincnitrate,HMTA，PEIandammoniumhydroxideasthegrowth-promotingmedia,togetsamplesbycontrollingofdifferentgrowthtemperatureandtime.PutthesamplesbyXRD,SEM,EDSandsoon,theresultsshowedthatthefoursamplesarewurtzitestructureofZnOnanorods,nanotubesarray,forests,andnanowirearraystructurepyramid,respectively.②Useionadsorption-chemicaldepositionmethod,bycontrollingthenumberofadsorption-reactiontogetadifferentamountofinorganicCdSquantumdots.Throughthepreparationofthebatteryandtaketheconversionefficiencyofthebatteryastheindicator,measuringtheoptimumsedimentarysamplesofdifferenttimes.Thenumberofthebestdepositionis40,35,30,30correspondingtotheZnOnanorods,nanotubes,forests,andnanowirearraystructurepyramid.BasedonthedifferentdepositionamountofZnOnanorodarrayofdarkcurrentperformanceanalysisofthebatteryindicatesthecompositereactionbetweenphotoproductionelectronicandelectrolytemainlyoccursonthesurfaceisnottheCdSdepositionofthesurfaceoftheZnO.③Use4kindsofarchitectureofZnOone-dimensionalnanomaterialsasthesensitizinglightanodeofthebattery,preparedofthesensitizedsolarcells,andgotthebestquantumdotsunderthedepositionofconversionefficiencyofsolarcell,respectively,ZnOnanorodarray:0.50%,ZnOnanotubearrays:1.08%,ZnOnanoparticlesforest:1.34%,ZnOconstructpyramid:1.60%.④ThroughtotheframeoffourkindsofpureZnOsampleslightabsorptiona