TiO2纳米复合结构的制备与宏观尺度组装-无机化学专业论文.docxVIP

II II 英文摘要 TiO2 纳米复合结构的制备与宏观尺度组装 Design synthesis of TiO2 composites and their macroscale assembly Abstract As an important semiconductor material, TiO2 is poisonless and harmless, having good chemical stability and good photocatalytic properties. It can product H2 from water under UV light, and have good photocatalytic degradation ability to the organic and inorganic pollutants in raw water. In this paper, we designed synthesis of composite with nano- TiO2, and increased the range of spectral absorption and good adsorption capacity. Above all, the results were briefly described as follows: By taking advantage of the structural affinity between bismuth oxohalide and TiO2, we successfully prepare a family of hybrid frameworks via the designated growth of bismuth oxohalide nanoplates on TiO2 nanoribbons, and propose them as sunlight-driven bifunctional photocatalysts for all-weather removal of pollutants. The structural variability of bismuth oxohalide allows the optical absorption of the hybrid framework to be monotonically tuneable across the visible spectrum. Meanwhile, the hybridization greatly increases the surface roughness of the frameworks and enables the frameworks to harvest more photons to participate in photocatalytic reactions. Furthermore, the hybridization establishes two potential gradients to promote the separation of photo-induced electron–hole pairs: the internal electrical field perpendicular to the wide surfaces of bismuth oxohalide nanoplates and across the semiconductor–semiconductor heterojunction. O wing to the synergetic effects of the permeable mesoporous architecture, the intense visible light absorption, and the efficient charge separation, the hybrid frameworks are capable of all-weather removal of pollutants: they utilize the inter-ribbon pores to gather pollutants in the dark (behaving as collectors) and they rapidly degrade the pollutants in the day (behaving as photocatalysts). In particular, the BiO Br@TiO2 framework exhibits very