ZnO纳米颗粒促进鲁米诺化学发光的研究及应用-化学专业论文.docxVIP

重庆大 重庆大学硕士学位论文 英文摘要 PAGE PAGE III ABSTRACT Chemiluminescence(CL) detection has many advantages, such as high sensitivity, relatively inexpensive instrument, wide calibration range and suitable for automation. Nanoparticles have a series of excellent properties. It has been reported nanoparticles have been applied in electronics, optics, energy and biological medicine. In recent years, nanoparticles as a catalyst used in the chemical luminescence, making the research of chemical luminescence is no longer confined to the level of molecules and ions, and to get rapid development. In this thesis, the review involves the concepts and characteristics of CL, photocatalytic properties of nanoparticles and the application of nanoparticles in the CL. In this thesis, ZnO nanoparticles(ZnONPs) as a catalyst in luminol–H2O2 CL system were explored. And luminol–H2O2–ZnONPs was applied for the analysis of H2O2 in rainwater. Selfdecomposition of H2O2 could cause signal of luminol–H2O2 CL unstable, and maked reproducibility poor. H2O2 is a strong oxidant, which can react with luminol, producing strong CL signals and high background values. In this study, it was found that in the presence of ZnONPs, ethylenediamine tetraacetic acid disodium (EDTA) and luminol could generate strong CL without other oxidizing agent. EDTA is a kind of chelating agent and used as electron donor commonly. Itself has no oxidation, good stability and solubility in water. A new CL system of luminol–EDTA–ZnONPs was established. In this paper, the effect of different particle sizes of ZnONPs on CL of luminol–EDTA was studied. Mechanism of the luminol–EDTA–ZnONPs CL systems was investigated. Moreover, a method for determination of caffeic acid and metal ion was developed. The main research results are as follows: ① Mechanism of luminol–H2O2–ZnONPs CL systems was investigated. Based on the ZnONPs amplifying a weak CL of luminol–H2O2 system, a simple and sensitive CL method was been developed f