不同酸掺杂聚苯胺膜的制备及其性能研究-应用化学专业论文.docxVIP

ABSTRACT ABSTRACT A conductive polyaniline coating was successfully polymerized on stainless steel in different acidic solution by means of electrochemical constant potential and characterized by many means. A conductive polyalliline coating was polymerized on the stainless steel in inorganic acid solution by means of electrochemical constant potential method ． The optimum process conditions were determined through chemical corroding proof and orthogonal experiment. A conductive polyalliline coating was polymerized on the stainless steel in organic acid solution by means of electrochemical constant potential method. The related synthetic condition how to effect the conductivity of polyaniline film was studied.The optimum process conditions were determined through the response surface methodology. The polyaniline films were characterized. Via FTIR ,analyzing method ,functional groups and conductive PANI films’configuration were studied.And the result shows that polyaniline prepared in organic acid is in the incidence of the redshift.The result of XRD analysis shows that the polyaniline films were composed of crystals.Scanning electron micrograph analysis their morphology,and the result shows that the polyaniline coating solution prepared in the organic acid is more uniform than the film prepared in an inorganic acid.The corrosion resistance of covered PANI were disscussed by anodic polarization curves and the result shows that corrosion resistance of stainless steels were improved significantly,when stainless steels were covered by polyaniline films . The films were plated nickel respectly through chemical method. Scanning electron micrograph analysis their morphology,the result shows test pieces with nickel ions are not uniform in an inorganic acid, and the film has cracks. the surface of the composite film in organic acid is uniform.The result of polarization curves shows that the stainless steels’s corrosion resistance were notablly improved.,when the