电泳沉积羟基磷灰石涂层的微波合成研究-纳米科学与技术专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 II II 响并不大，均有 HA 存在，为获得致密度更高的涂层，电极间距选择 15mm。 微波合成条件下，电泳沉积最优参数为：沉积时间为 5min，沉积电压为 100V， 电极间距为 15mm。将此参数下制得的涂层进行模拟体液浸泡实验，浸泡 8 天后在 HA 涂层表面能够诱导生长出类骨磷灰石，说明制备的 HA 涂层具有生物活性。 关键词：钛合金；纳米羟基磷灰石涂层；电泳沉积；微波合成；生物相容性 III III Abstract Due to low self-bonding strength, bonding strength and large particle size, hydroxyapatite (Ca10(PO4)6(OH)2, HA) / titanium alloy composite material is restricted in medical applications. In this paper, a submicron HA coating was fabricated on medical Ti6Al4V surface by the combination of electrophoretic deposition and microwave synthesis. The parameters of HA suspension, electrophoretic deposition and microwave synthesis were studied and optimized. The morphology, phase structure and biological properties of the coating were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD) and SBF experiment. Using n-butanol as a dispersion medium, adding 12mL/L triethanolamine and adjusting pH value to 6, the suspension was stable and suit for obtaining a uniform coating by electrophoretic deposition with concentration of 20g/L. And the suspension can meet the requirements of depositing HA coating. By studying the parameters of electrophoretic deposition, the results showed that the amount of coating deposition increased with the deposition time, the early growth was rapid, then the rate slowed down. Poor coating uniformity firstly were obtained, due to the late suspended particulates have time to look for space, the coating became uniform with deposition time increasing. The amount of coating deposition was increasing as the voltage increased while the growth rate became slow. In order to obtain a more uniform coating, the loading voltage should be tens of volts lager than the high threshold voltage driving the particle. As the electrode distance decreased, the amount of coating deposition was increasing while the increasing rate began to be gentler afterwards. By studying the parameters of microwave synthesis, the r