超级富勒烯及其醇化物的分离、表征和功能研究-化学专业论文.docxVIP

西南科技大学硕士学位论文第 西南科技大学硕士学位论文 第 PAGE IV 页 西南科技大学硕士学位论文第 西南科技大学硕士学位论文 第 III 页 Abstract Fullerene has been found to be an extremely promising material in various fields due to its unique properties for recent 30 years. Fullerene has a potential value in many fields because of its unique properties and highly symmetric structure. In this paper, we prepared super fulleols that the water-soluble derivative of super fullerenes by using super fullerenes. It can be inferred that super fullerenes is a highly symmetric hollow nanosphere from NMR, TEM, SEM and the size varied from 5 -20nm. Characterizing their unique spectral properties by IR, Raman, Uv-vis, Fluorescence and XPS and so on. In this paper we studied the interaction mechanism between super fullerols and ctDNA by combined spectral methods, viscosity method, thermodynamic method, melting method, Scatchard method in simulation physiological conditions (pH=7.40). And their combine ratios, combine constants and thermodynamic functions were also calculated. In the same coditions (pH=7.40), we used spectral methods, viscosity method, thermodynamic method to studied the interaction mechanism between super fullerols and BSA. In this paper, we also studied the Hydroxyl radical scavenging of super fullerols. Super fullerene is a new caorbon nanomaterial and testing their absorbing properties by use FTR , we found that super fullerene showed good absorbing abilities, it can be use as a potential absorbing materials. Key words: super fullerene, super fullerol, wave- absorbing, ctDNA, BSA 目 录 HYPERLINK \l _bookmark0 1 绪论 1 HYPERLINK \l _bookmark1 1.1 引言 1 HYPERLINK \l _bookmark2 1.2 富勒烯的研究状况 1 HYPERLINK \l _bookmark3 1.3 富勒烯制备方法 3 HYPERLINK \l _bookmark4 1.3.1 石墨电弧放电法 3 HYPERLINK \l _bookmark5 1.3.2 热蒸发石墨法 5 HYPERLINK \l _bookmark6 1.3.3 火焰燃烧法 6 HYPERLINK \l _bookmark7 1.3.4 催化热分解法（CVD） 6 HYPERLINK \l _bookmark8 1.3.5 其它方法 7 HYPERLINK \l _bookmark9 1.4 富勒烯的醇化、分离、提纯方法 7 HYPERLINK \l _bookmark10 1.4.1 醇化方法 8