优秀（设计）二氧化碳加氢合成甲醇铜基催化剂的制备及催化性能的研究.docVIP

co2加氢合成甲醇是循环利用co2的途径之一，而高效催化剂是提 高转化率和选择性的关键问题。本文用并流共沉淀的方法制得 GO/CuO-ZnO-Al2O3 催化剂，采用 XRD、BET、SEM 和 H2-TPR 表征方 法对催化剂的结构性能进行了表征。探究了 GO的加入对CuO-ZnO-Al2O3 催化剂催化性能的影响，同时还研究Y不同配比的GO对其反应性能的 影响，在固定床反应器上对上述催化剂进行了评价。结果显示，GO对催 化剂的催化性能产生了 一定的影响，且儿种不同配比的 GO/CuO-ZnO-Al2O3催化剂在反应温度为250 °C、压力为3 MPa, H2和 (302摩尔比为3:1的条件下，分别进行评价后相比较CuO-ZnO-Al2O3催化 剂的反应活性发现，催化剂的甲醇选择性增加，转化率降低，且转化率 随着GO的量增加而减小，而甲醇选择性随着GO的量的增加而增人。 其中，GO量为10%吋制得的GO/CuO-ZnO-Al2O3催化剂选择性最高，达 到了 58.2%。 关键词：CO2加氢；氧化石墨烯；铜基催化剂；甲醇选择性 Abstract CO2 Hydrogenation is one way to recycle CO2, and efficient catalyst to improve the conversion and selectivity of key issues. In this paper, co-precipitation and stream prepared as GO / CuO-ZnO-Al2O3 catalyst using XRD, BET，SEM and H2-TPR characterization of structural properties of the catalysts were characterized. GO explores the impact of the addition on the catalytic properties of CuO-ZnO-AhC^ catalyst, but also the effects of different proportions GO their response performance, in a fixed bed reactor of the above-mentioned catalysts were evaluated. The results show, GO on the catalytic performance had a certain influence，and several different ratio GO / CuO-ZnO-Al2O3 catalyst at a reaction temperature of 250 °C，a pressure of 3 MPa, H2 and CO2 molar ratio of 3: under condition 1，were evaluated after comparing CuO-ZnO-Al2O3 catalyst reactivity found that methanol selectivity of the catalyst is increased, the conversion rate is reduced, and the conversion increases with the amount of GO decreases，and methanol selectivity with the increase of the amount of increase of GO. Wherein, GO amount of 10% obtained in GO / CuO-ZnO-Al2O3 catalyst selectivity highest，reaching 58.2%. Key Words: CO2 hydrogenation; graphene oxide; copper-based catalyst; methanol selectivity 目录 TOC \o 1-5 \h \z ^1^^ 1 HYPERLINK \l bookmark2 \o Current Document \h 1.1研究背景 1 HYPERLINK \l bookmark3 \o Current Document \h 1.2国内外研究现状 2 1.2.1国A外甲醇合成研究现状 2 1.2.2国内外甲醇合成催化剂研究现状 2 HYPERLINK \l bookmark4 \o Current Document \h 1.3铜