分子筛抗菌剂制备及抗菌性能分析-高分子化学与物理专业论文.docx

桂林理工大学硕士学位论文 桂林理工大学硕士学位论文 桂林理工大学硕士学位论文 桂林理工大学硕士学位论文 PAGE PAGE VI III III ABSTRACT Natural stellerite contains certain amount of impurities, and the adsorption ability is weak. So it is not suitable for the carrier of the antibacterial agent, but can be used as the raw material of preparing for excellent carrier Zeolites; While as an antibacterial agent and feed additive, potassium diformate have a good antibacterial effect, but it cannot reach to play an effective role at the end of the intestine, due to its rapid decomposition and absorption in the gastrointestinal. Making full use of the advantages of the two, we make carrier molecular sieve adsorb the potassium diformate to achieve the purpose of sustained-release it. So as to improve the pH at the end of the intestinal tract, play a role to reduce harmful bacteria andincrease beneficial bacteria. Taking natural stellerite as raw material to prepare A, X and P zeolites, as a carrier adsorb potassium diformate, prepare the sustained-release performance of zeolite antibacterial agents. The results show that: Reaction of 800 mesh stellerite and a concentration of 15 % hydrochloric acid by the ratio of solid to liquid ratio of 1:3, for 2 h at 80 ℃. Most of its impurities are removed; the structure is broken into amorphous. It can be used as precursors for the preparation of high quality zeolite. After filtration of the precursor by an alkali-soluble, the best preparation conditions were: Zeolite A , n(SiO2/Al2O3.)=2, n(Na2O/SiO2)= 1.1, n(H2O/Na2O)=35-45, for 6 h at 90 ℃; Zeolite X as raw gel aging for 12 h at room temperature, n(SiO2/Al2O3)=3, n(Na2O/SiO2)=1.1-1.2, n(H2O/Na2O) =30-40, for 8 h at 95 ℃; Zeolite P, n(SiO2/Al2O3)=3.5, n(Na2O/SiO2)=15, n(H2O/Na2O)=40-45, for 7 h at 95 ℃. Characterization results of A, X and P zeolites were: Zeolite A is cube crystal shape as cube, 98 % of the degree crystallinity, the volume average particle diameter of 3.72 μm, the characteristic peaks of IR at 3 442.82, 1 650.25, 1 0