车载吸附储氢系统的设计与研究-制冷及低温工程专业论文.docxVIP

上海 上海交通大学硕士学位论文 第 第 II 页 向导热系数最高提高了61倍左右，而径向导热系数则提高了16倍左右， 且提高了物理吸附性能。对所建立的复合固化吸附储氢测试系统的传热 以及吸附特性进行仿真，采用所研制的新型固化混合吸附剂，吸附床在 吸附过程中，在相同的30℃的冷却条件下，在同一时刻，固化混合吸附 剂吸附床内外温差比散装镧镍合金低约8℃，其最大吸附储氢速率可以提 高24％，达到平衡时间相对提高了41%。 关键词：储氢，吸附式储氢，传热强化，复合固化吸附剂，数值模拟 第 第 III 页 The design and characteristics research of hydrogen adsorption storage applied to hydrogen vehicle ABSTRACT As the pollution on the environment and resources are limited, Fossil energy is facing the challenge of renewable clean energy which could be efficient used. Hydrogen, as a storage material of rich and wide variety of sources, is getting the peoples attention. Three issues need to be paid attention on the use of hydrogen, which are hydrogen energy extraction, storage and transportation and application. In which the hydrogen storage and transportation is a key point and has been paid more attention international. At present there are many kinds of technologies in hydrogen storage which includes high-pressure gaseous hydrogen storage technology, low temperature liquid hydrogen storage, metal hydride adsorption of hydrogen storage, carbon nanotube adsorption of hydrogen storage, organic liquid hydride hydrogen storage, etc. In which the metal hydride adsorption of hydrogen storage technology has the advantages of a high volume storage density, safer because of the atomic states of hydrogen, as well as needn’t strict insulation relative to the liquid 第 第 PAGE VII 页 hydrogen storage. At the same time, there are disadvantages of metal adsorption of hydrogen storage technology. The weight hydrogen storage density is pretty low and the thermodynamics have a poor performance, while its powder process also leads to the performance instability. In order to solve the problems for mental adsorption of hydrogen storage technology; this thesis designed a new composite solidification adsorbent system, and developed kinds of adsorbent in different content ratio and solidification method. Hotdisk Thermal Analyzers was