共振离子型聚砜阴离子交换膜的制备及性能化学工程专业论文.docxVIP

共振离子型聚砜阴离子交换膜的制备及性能Preparation 共振离子型聚砜阴离子交换膜的制备及性能 Preparation and Characterization of Polysulfone Anion Exchange Membrane Based on Resonant Ionic Groups Abstract Anion exchange membrane fuel cell(AEMFC)has recently attracted tremendOUS attention because its fast oxygen reduction reaction in basic operating condition allows the use of non—precious catalyst or transition metal oxides in place of platinum，making AEMFC more cost effecfive；also．fuel crossover and carbonate crystallization Can be effectively weakened and avoided．Currently．10w ionic conductivity and inferior chemical stability of AEM ar e two major problems restricting practical application of AEMFC．Therefore，modification of existing AEM or developing new membrane structure is highly important for the development of AEMFC．Imidazolium or guanidinium anion exchange membrane has dual advantages of conductivity and chemical stability thanks to strong basic and co巧ugated structure of ion exchange groups．In this dissertation，we explored the influence of resonance on membrane’S chemical stability by modulating resonance level of cations．Resonance can possibly promote charge delocalization of cations and reduce its interaction with hydroxide ions SO that alkali-resistance ofmembrane Can be improved．Main contents ale as follows： Firstly．we introduced guanidine into imidazole molecule tO synthesize binary ionic reagent 2-(1，1，3，3-tetramethylguanidine)-imidazole，also named guanidimidazole(GIm)， which has double resonance structure．Then，we prepared guanidimidazole-quantemized anion exchange membrane(PSf-MIm-GImOH)using GIm and 1-methylimidazole(MIm)as quaternizing agent simultaneously．PSf二MIm—GImOH membrane had decent anti—swelling effect SO that membranes fabricated with and without GIm exhibited similar ion exchange capacity(IEC)and conductivity(ca．14．83 VS．16．05 mS‘cm叫)but very different swelling ratio(ca．23 VS．3 8％)．Furthermore．PSfl 40．MIm．GImOH membrane showed impressive alkali stability：its conductivi