半晶聚合物的应力应变行为及其与形态结构的关系材料加工工程专业论文.docxVIP

四川大学博士学位论文研究发现，此时试样的应力应变行为与常规试样有着显著的区别，弹性形变和 四川大学博士学位论文 研究发现，此时试样的应力应变行为与常规试样有着显著的区别，弹性形变和 屈服过程之后，均表现出较为明显的成颈和撕裂特征。就断裂特性而言，长支 链的LDPE的断裂韧性We和比塑性功p％均显著的低于HDPE和LLDPE；能 量拆分的结果表明聚烯烃材料断裂过程的We和B％及其断裂行为的差异主要决 定于材料成颈．撕裂阶段。填充体系的we值普遍低于纯树脂，受玻璃微珠粒径 的影响不大，而随玻璃微珠含量的提高而降低，两pw口值随着玻璃微珠的加入 而降低，填充量较低时，GB／LLDPE，GB／PP体系pwp值增高，随着含量的增 高，即，口随之下降。研究还发现采用裂纹开口位移的方法也可有效的评价玻璃微 珠填充聚烯烃体系的断裂韧性。 关键词：聚烯烃，聚酰胺6，应力应变行为，测试条件依赖性，形态结构，二次 屈服，断裂特性 m 聚合物的应力应变行为及其与形态结构的关系Stress-strain 聚合物的应力应变行为及其与形态结构的关系 Stress-strain behaviors of semicrystalline polymeric materials and their relationship with morphologies Major：Material Processing Engineering Postgraduate：Wei YANG Supervisor：Pro￡Ming-Bo YANG ABSlRACT： On the basis of a brief introduction of the deformation behavior and yielding characteristics including the unusual double yielding phenomenon of polymers， especially semicrystalline polymers，this thesis reviewed the influencing factors of deformation behavior ofpolymers from the temperature activated molecular mobility, stre$s activated molecular mobility,effect ofbeating history and dependence ofstress strain behavior of polymers，polymer blends and polymer composites on the slructures and morphology and forward the purpose and arrangement ofthis study． Firstly the dependence of stress strain behavior of polyolefin 011 the test conditions was investigated．1flle results showed that at room temperature high density polyethylene(HDPE)，isotactic polypropylene(iPP)and enpolypropylene (cPP)presented the typical 5neSS strain behavior of semicrysta／line polymers in a wide range of tensile velocifies，no yielding poim Was shown for low density polyethylene(LDPE),and the unusual double yielding behavior and distinct strain hardening phenomenon was observed for linear low density polyethylene(LLDPE)． With the tensile velocity iIlcrc弱in舀the basic characteristics of these stress stain behavior were unchanged while the overall s11ess main clnve$were raised and elongation at break(￡b)depressed．In a eA：rtain range of tensil