改性双季铵盐的合成及其在油田水处理中的应用研究应用化学专业论文.docxVIP

英文摘要Subject：Synthesis 英文摘要 Subject：Synthesis and Application of Modified Bis·quaternary Ammonium Salt In oilfieid Wastewater Treatment Speciality：Applied chemistry Name： zh。u Juan(signature)2叁坐j!!!竺竺 Instructor：Zhang Ningsheng(signature ABSTRACT SRB，TGB and other microbes in oilfield reinjection water could cause corrosion of injection equipments and pipelines．However，the microbes would contain genes conferring resistance on biocide，resulting in increasing in MIC of common biocide and treatment costs and even that the treated water couldn’t meet the criteria．Aiming at solving this problem，one novel biocide，the modified bis-quatemary ammonium salt MHTD Was synthesized by using epichlorohydrin(ECH)，N，N-dimethyl dodecyl amine(DMA 1 2)and metronidazole(MDZ)as raw materials．In this paper，the synthesis process conditions，bactericidal properties，corrosion inhibition,surface activity of MHTD were studied，as well as compatibility with other wastewater treatment agents．The results show that： It took three steps to synthesis MHTD．First，DMAl 2 combined晰也hydrogen chloride to form N，N-dimethyl dodecyl amine hydrochloride(DMAH)．Second，DMAH reacted嘶tll ECH to produce the intermediate product of CHAC(N-(3一chloro一2一hydroxypropyl)-N， N-dimethyl dodecyl ammonium chloride)．At last,MHTD Was obtained from the reaction of CHAC and MDZ．111e yield of CHAC could reach the best of 93．5％in the conditions of reaction temperature at 40 oC and the molar ratio of reactants n(DMAH)：n(DMAl2)：n(ECH) at 1：0．1 5：1．1 0．The best yield of MHTD reached 82．4％in acetonitrile诵tll the conditions of the reaction temperature at 80 oC，the molar ratio of reactants n(MDZ)：n(CHAC)at 1．2：1 and reaction time of 1 2 h．The product structure of MHTD Was detected by IR spectrum and melting po硫apparatus，the result WaS coined wim the primary design． The results of the bactericidal properties study show that：the bactericidal rate is increasing、航tll the concentration of MHTD；the bactericidal rates could reach 99．99％and 99．1