介孔二氧化硅的改性及其调湿性能的研究-材料工程专业论文.docxVIP

浙江理工 浙江理工大学专业硕士学位论文 介孔二氧化硅的改性及其调湿性能的研究 万方数据 万方数据 本文制备的调湿材料具有工艺简单、调湿性能优异、调湿稳定性和重复性好等特点。 对于湿度敏感性强的有机质文物具有积极地保护作用，可为文物创造一个恒湿干净的存放 环境，对我国文物的预防性保护工作具有积极的意义。 关键词：调湿；介孔；二氧化硅；文物环境；孔径；吸附 II Abtract Environment relative humidity is important for our daily life and industry. The changes of environment relative humidity cause the negative consequences and difficulty regulation to cultural relics, drugs, jewelries and so on. Organic cultural relics are more sensitive to environment relative humidity, such as fabrics. Formerly, more attention was paid to absorption (desorption) rate and amount. We hope to prepare a kind of humidity control materials, which has a high level of absorption rate and amount. In previous years, our group has prepared 8 different kinds of humidity control materials, such as composite humidity control paper, composite humidity control paperboard, the porous composite resin and so on. However, after application, we have an knowledge that the stability and repeatability of materials are more important than absorption (desorption) rate and amount. Because polymer materials, inorganic mineral materials and inorganic/organic composite materials have characters of poor stability and controllability of structure, the stability of humidity control properties are impossible According to the special requirements of f textile cultural relics, a mesoporous silica with hexagon pore structure was made. The modification methods were metal doping and pore bearizing. The effect of pore structure on humidity control properties was discussed. Besides, by discuss the relationship between absorption amount and equilibrium humidity as a reference of humidity control accuracy, we can evaluate humidity control properties comprehensively. The conclusions are as following. （1）SBA-15 is prepared in acidic medium, with P123 as template. It has hexagon pore structure, with high specific surface area and entrance. The average pore size is 6.03 nm. Equilibrium moisture is 59.7%, which