焦化生化外排水中COD的电化学深度处理研究-环境工程专业论文.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Coking wastewater is a typical refractory industrial wastewater with high biological toxicity. The advanced treatment and reuse of bio-treatment outflow of coking wastewater attracts more attention. Electrochemical methods have been widely used in the field of water treatment because of its advantage of little secondary pollution and easy operation. In this paper, advanced treatment of bio-treatment coking wastewater by electrochemical technology was studied. The reaction mechanism of electro-catalytic oxidation of quinoline, which is the typical pollutant in coking wastewater, was preliminary discussed as well. The main conclusions were drawn as follows： When initial pH was 8, current density was 7 mA/cm2 and plate distance was 3 cm, the COD removal of electric flocculation was 41.6% with iron plate anode and graphite plate cathode respectively. Aeration rate had little effect on COD removal. Otherwise the COD removal of coagulation was 33.0% when the initial pH was 8, the dose of PFS was 0.3 mL/L, reaction time was 6 min and still time was 3 min. Polyacrylamide had no obvious effect on COD removal. When initial pH was 3, current density was 5 mA/cm2 , dosage of H2O2 was 1 mL/L and plate distance was 1 cm, the COD removal of electro-fenton was 76.5% with iron plate anode and graphite plate cathode respectively. When initial pH was 8, current density was 10 mA/cm2, and plate distance was 1 cm, the COD removal of electro-catalytic oxidation system was 100% with idium modified Ti anode and graphite plate cathode respectively The cost of coking wastewater treatment by coagulation、electric flocculation、 electro-fenton and electro-catalytic oxidation was 0.95 yuan、0.30 yuan、2.62 yuan and 1.67 yuan. The COD of coking wastewater after advanced treatment by electric flocculation cooperated with electro-catalytic oxidation could meet with Code for design of industrial recirculating cooling water treatment. However, the sa