金属罐内涂层破损区气相定位检测局部电化学探头技术的研究-分析化学专业论文.docxVIP

万方数据 万方数据 bottom area and sidewalls were detected respectively. The result showed that this device could accurately locate and evaluate the status of coating defects in planar and cylindrical area in metal can in atmosphere, and had a high resolution and precision. In addition, this paper also studied coating with different defect size, and the result showed that under the same condition, the larger the damaged area, the lower the impedance values. The result also illustrated that this probe can distinguish different sizes of coating defects with high sensitivity. In summary, the local electrochemical probe had high practical value in laboratory. Key words: Local electrochemical probe, Metal can, Coating defects, Open circuit potential， Electrochemical impedance spectroscopy iv 目 录 1 前言............................................................................................................................1 1.1 金属包装罐的广泛应用......................................................................................................1 1.2 金属包装罐内涂层的作用................................................................................................. 2 1.3 金属包装罐内涂层的防腐蚀机理..................................................................................... 3 1.4 金属罐内涂层腐蚀防护问题............................................................................................. 4 1.5 有机涂层防腐性能的研究与评价方法............................................................................. 6 1.5.1 常规检测法...............................................................................................................6 1.5.2 电化学法...................................................................................................................6 1.6 课题研究意义和研究内容............................................................................................... 10 1.6.1 课题研究意义..........................................................................................................10 1.6.2 课