碳纤维表面局部熔覆Al涂层的制备及其氧化工艺研究.docxVIP

碳纤维表面局部熔覆A1涂层的制备及 其氧化工艺研究 杨建军赵雪妮王旭东张靖王婉英张黎何富珍 杨柯刘军鹏 陕西科技大学机电工程学院 摘要： 采用局部熔覆法复合水/化学氧化法对碳纤维(CF)表面A1涂层的制备及氧化 工艺进行了研究，并采用扫描电子显微镜(SEM)、X-射线能谱仪(EDS)和X- 射线衍射仪(XRD)等对CF表面涂层的微观形貌和物相组成进行了表征.研究表 明：采用局部熔覆法可以制备得到A1涂层，当拉丝速度为10mm/s时涂层表面形 貌优良，能够实现对基体CF的完全包覆；当熔覆次数由1次增加至3次时获得的 涂层致密均匀，厚度由0. Sum增加至3. lum;研究还发现采用水氧化法可以实 现A1涂层向AI2O3的转变，而采用化学氧化法时，CF表面的A1涂层存在大量溶 解的现象. 关键词： 碳纤维；A1涂层;局部熔覆; 氧化工艺; 作者简介：杨建军(1993-)，男，陕西西安人，在读硕士研究生，研究方向： 牛物复合材料 作者简介：赵雪妮(1974-)，女，陕西礼泉人，教授，博士，研究方向:生物复 合材料， HYPERLINK mailto 收稿日期：2017-07-10 基金：国家自然科学基金项目 Study on the partial cladding process and oxidation properties of Al coating on the surface of carbon fiber YANG Jian-jun ZHAO Xue-ni WANG Xu-dong ZHANG Jing WANG Wan-ying ZHANG Li HE Fu-zhen YANG ke LIU Jun_peng College of Mechanical and Electrical Engineering, Shaanxi University of Science Technology; Abstract： In this experiment， the preparation and oxidation process of Al coating on carbon fiber (OF) surface were studied by the method of partidl cladding combined water/chemical oxidation method. The microstructure and phase composition of CF surface coatings were characterized by scanning electron microscopy (SEM) , X-ray energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) . The results show that the Al coating can be prepared by partidl cladding. When the control drawing speed is 10 mm/s, the surface morphology of the coating is good, and the coating of the matrix CF can be compl e tely coated. Whe n the cl add ing times in creased from 1 time to 3 times, the coating was compact and unifom, and the thickness increased from 0 8 u m to 3. 1 u m. It is also found that the Al coating can be transformed into ALOa by water oxidation method, but the Al coating on the surface of CF has a large number of dissolution phenomena by chemi cal oxi dati on method. Keyword： carbon fiber; Al coating; partial cladding; oxidation process; Received： 2017-07-10 0引言 碳纤维（CF）作为一种低密度、高强度、高模量比的纤维材料，具有良好的耐磨 性、耐热性、尺寸稳定性和耐酸碱性，已成为一种极具发展潜力的增强材料[1-4