钴基石墨烯复合材料的制备及电化学性能研究-化学工程专业论文.docxVIP

钴基石墨烯复合材料的制备及电化学性能研究Preparation 钴基石墨烯复合材料的制备及电化学性能研究 Preparation and Electrochemical Properties of Cobalt-based Graphene Composites Abstract Cobalt-based graphene composites have a wide range of applications in the fields of energy storage and conversion,such as lithium ion batteries，supereapacitors，fuel cells， electrolysis of water． Since cobalt-based graphene composites exhibit preferable electrochemical performance and are relatively inexpensive，they are regarded as one of the most promising materials to substitude noble metal in some applications．nle purpose of this paper is to prepare novle structured cobalt—based graphene composites to meet the needs of efficient oxygen evolution reaction and high performance supercapacitor by a green and efficient electrodeposition method． Firstly，CoS@eRG(electrochemically reduced graphene)electrodes were successfully prepared by using a two—step electrodeposition method．The thin film of CoS@eRG、杭tll thickness of 1 pan was composed of graphene and CoS nanosheets,which were nicely integrated together with open channels．砀e CoS@eRG composites exhibit an impressive specific capacitance of 3386 F／g at a current density of l A／g，2．6 times that of the CoS electrode．A CoS@eRG 0 activated carbon asymmetric capacitor exhibits maximum energy density of 29 Wh／kg and power density of 40 kW／kg．Furthermore，70％capacitance retention is obtained after 1 0 000 cycles at a current density of 1 A／g． Secondly，NixC02xOH6x@eRG electrodes were prepared by a two-step electrodeposition method．111e thickness of nickel．cobalt hydroxide nanosheets iS about 1 0-20 nm．The graphene sheets and nicke-cobalt hydroxide nanosheets closely anchored together．The Tafel slope of NixC02。OH6x@eRG electrode iS 67 mY／dec，which iS 1 5．2％lower than that of NixC02xOH6x electrode．111e overpotential of NixC02xOH6x@eRG electrode is only 280 mV at a current density of 10 mAJcm2，which iS 12．5％lower than that ofNixC02xOH6x electrode． Finally．NiC0204@eRG electrodes were prepared