四元共聚物型水泥降失水剂的合成.pdfVIP

两性离子聚合物 PADAA的合成 摘 要 两性离子聚合物因其独特的分子结构和良好的应用性能，近几年在石油工业中 得到广泛的应用。本文通过对两性离子聚合物处理剂作用机理的研究，利用正交实 验设计，采用自由基水溶液聚合，以氧化还原体系为引发剂，合成了四元共聚物， 单体为丙烯酰胺（AM）、2-甲基-2烯丙基氯化按(DMDAAC)、2丙烯酰胺基-2-甲基 丙磺酸钠(AMPS)、丙烯酸(AA). 本文研究了反应条件(单体浓度，引发剂，单体配比等)对产品分子量及性能的 影响;采用红外光谱法表征了产品的分子结构;就其聚合产品水溶液的抗温性及pH 值对特性粘度的影响进行了研究;评价了共聚产品在固井水泥中的降失水性.实验 表明，本文所合成的产物耐温性好，具有较强的降失水能力,是一种具有较强降失 水性的新型两性离子聚合物。 关键词：两性离子聚合物 抗温性 降失水剂 II 两性离子聚合物 PADAA的合成 THE SYNTHSIS OF CEMENT FLUID LOSING ADDTIVES BY DMDAAC/AMPS/AM/AA Abstract In petroleum industry ， amphiprotic polymers are widely used for their better properties. This paper,copolymerized the amphiprotic polymer based on the analysis of principleanalysis of amphiprotic polymers operation.. Through orthogonal design and redox iliitiation and by free radical polymerization in aqueoussolution ，a new kind of amphiprotic polymer was synthesized. The effects of monomer mixture concentrations，initiator dosage and reaction on molecular weight·were discussed in this paper.The molecular structures of copolymer were ascenained through infrared absorption spectrum method. The influences ofsalt ， temperature and PH value ofthe aqueous products were studied in this paper;The fluid loss control ability and the inhibitionability The results indicate that the Product with certain molecular references is well with the ability of fluid loss control and inhibition. Product is a kind of amphiprotic polymer with both fluid loss control andinhibition ability in fact. Key words ：amphiprotic polymer anti-high temperature fluid loss additives III