计时吸附电位分析法测定KH2PO4中超痕量Fe（Ⅲ）.pdfVIP

维普资讯 第 16卷第 2期 青 岛 大 学 学 报 V0I 16No2 2001年 6月 JOURNALOFQINGDAO NIvERsITY IJn200l ArticleID2001 DERERM INATION OFULTRATRACE IRON IN POTASSIUM DIHYDR0GEN PH0SPHATE BY DERIVATIVE ADSORPTION CHRONOPOTENTIOMETRY GsoHus ，LiuKun (MedicalCollege，QingdaoUniversity，QingdaoShsndong，266021China) Abstract：A sensitivederivativeadosrptionchronopotentiometrymethodforthedeterminationof uhratraceFe(III)inKH2P04hasbeenstudiedbasedontheformationoftheocmplexFe(III) with2一(5bmmo-2一pyridyIaze)5-diethy lanminophenol(5-Br-PADAP)Theinfluenceof KH2P onthesignalofthereductionofthecomplexFe(III)with5-Br-PADAPwasdis— cussed Fe(III)wasseparatedfrom thesolutioncontainingKH2PO4byusingtheeoprecipita— tionofFezS3withPbSpriortoe[ectmchemicaldetection Themethodwasusedfordetermina tionofultratraceFe(III)inKH2P04crystalsanditssaturatedliquorwithsatisfactoryresults Keywords：potentiometry；iron；ulratraceanalysis；potassium dihydrogenphosphate；coprecipita tion CLCnumber：0625．7O65621 Documentcode：A IntheprocessofculturingKH2P。4crysta1．the hangingmercurydropelectrode(HMDE)． existenceofsmallamountsofmetalionsmay influ— Theelectrodeprocess hasbeenappliedtothede encethequalityofthecrysta1．Itisthereforeneces— temr inationofFe(III)infoodsamplesbyadsorption sarytofindasimpleandhighlysensitivemethodto chmnopotentiometryl Thismethodisnotusefu】for detemr inetheseions，suchasSn(IV)．Ga(II1)， thedetemr inationofFe(III)inKH2P04becausethe (IV)andFe(III)．Anodie-strippingvoltam